triphenylindium

Base Information

• Chemical Name: triphenylindium
• CAS No.: 3958-47-2
• Molecular Formula: C18H15In
• Molecular Weight: 346.137
• Mol file: 3958-47-2.mol

Synonyms:

Chemical Property of triphenylindium

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenylindium

There total 7 articles about triphenylindium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

indium(III) chloride + phenylmagnesium bromide (100-58-3) → triphenylindium (3958-47-2)

Guidance literature:

In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.jorganchem.2017.10.013

Reference yield:

indium(III) chloride + phenyllithium (591-51-5) → triphenylindium (3958-47-2)

Guidance literature:

In tetrahydrofuran;

DOI:10.1002/chem.201403736

Reference yield:

indium(III) chloride (10025-82-8) + phenyllithium (591-51-5) → triphenylindium (3958-47-2)

Guidance literature:

In not given; under Ar; soln. of PhLi (3 equiv.) in THF or hexane or Et2O added slowly(15-30 min) to cooled (-78°C) soln. of InCl3 in THF; stirred for 30 min; warmed to room temp.; according to H. C. Clark, A. L. Pickard, J. Organomet. Chem. 8 (1967) 427;

DOI:10.1021/ja004195m

upstream raw materials:

diphenylmercury(II)

indium

triphenylbismuthane

indium(III) chloride

Downstream raw materials:

triphenylmethyl alcohol

1,1-Diphenylmethanol

benzophenone

1,3,3-triphenylpropan-1-one

Refernces

• 1、 Maslennikov,Malysheva,Spirina,Klement'eva. "Oxidation of indium with triphenylbismuth in polar solvents". . p. 1763 - 1765. Retrieved 2005.
• 2、 You, Shengyong,Xiao, Ruian,Liu, Haiyi,Cai, Mingzhong. "A phosphine-free, heterogeneous palladium-catalyzed atom-efficient carbonylative cross-coupling of triorganoindiums with aryl halides leading to unsymmetrical ketones". . p. 13862 - 13870. Retrieved 2017/11/27.
• 3、 Mosquera, ngeles,Frnandez, M. Isabel,Lopez, Moiss Canle,Sestelo, Jos Prez,Sarandeses, Luis A.. "Nonsymmetrical 3,4-dithienylmaleimides by cross-coupling reactions with indium organometallics: Synthesis and photochemical studies". . p. 14524 - 14530. Retrieved 2015/01/09.