Indium trichloride

Base Information

• Chemical Name: Indium trichloride
• CAS No.: 10025-82-8
• Molecular Formula: InCl3
• Molecular Weight: 221.179
• Hs Code.: 28273990
• European Community (EC) Number: 235-764-6
• UNII: 31JB8MKF8Z
• Nikkaji Number: J43.827H
• Mol file: 10025-82-8.mol

Synonyms:(111)indium chloride;(113)indium chloride;indium chloride;indium trichloride;indium trichloride (113);indium trichloride, 111In-labeled;indium trichloride, 113In-labeled

Chemical Property of Indium trichloride

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 1Pa at 25℃
• Melting Point: 262 °C (dec.)(lit.)
• Boiling Point: 300 °C
• Flash Point: 300°C subl.
• PSA: 0.00000
• Density: 3.46 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 219.810437
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Indium(III) chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 36/37/38-34-29-22
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[In+3]
• Description: Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.
• Uses: Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3 In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium. Indium(III) chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis.

Technology Process of Indium trichloride

There total 44 articles about Indium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + indium (7440-74-6) → indium(III) chloride (10025-82-8)

Guidance literature:

With water; starting with slightly wettened In without heating, then at 120 to 140°C, by adding more water;

Reference yield:

indium (7440-74-6) + chlorine (7782-50-5) → indium(III) chloride (10025-82-8)

Guidance literature:

in dry Cl2-flow;

Reference yield:

InCl2(1+) (29790-97-4) → indium(III) chloride (10025-82-8)

Guidance literature:

With lithium chloride; In N,N-dimethyl-formamide; Ar atmosphere, 25°C, ionic strength 1 M (LiClO4); not isolated; potentiometric monitoring (3 mass-% indium amalgam indicator electrode), estimation of stability const. of InCl3 in DMF;

upstream raw materials:

sulfur dioxide

chlorine

thionyl chloride

tetrachlorosilane

Downstream raw materials:

indium chloride

indium monochloride

indium

{InCl₃(C₆H₅C(O)CH₃)2}

Refernces

• 1、 Matskevich. "". . p. 955 - 958. Retrieved 2007.
• 2、 Chen, Lin,Song, Jie-Guang,Yan, Dong-Liang,Qin, Yue-Ning,Wu, Bo-Lin. "Synthesis of indium tin oxide (ITO) nanoparticles from the hydrolyzate of a composite complex salt". . p. 731 - 733. Retrieved 2008.
• 3、 Ilyukhin,Petrosyants. "Supramolecular ensembles of indium thiocyanates with the [K(18C6)] + complexes". . p. 566 - 571. Retrieved 2009.
• 4、 Steiner, Udo,Reichelt, Werner. "Chemical vapor transport of ternary indium molybdates". . p. 1877 - 1884. Retrieved 2005.
• 5、 Túnez,Orosco,González,Ruiz, M. Del C.. "Kinetic study on the chlorination of indium oxide". . p. 151 - 156. Retrieved 2011.
• 6、 Park, Kye-Sung,Sato, Wakao,Grause, Guido,Kameda, Tomohito,Yoshioka, Toshiaki. "Recovery of indium from In2O3 and liquid crystal display powder via a chloride volatilization process using polyvinyl chloride". . p. 105 - 108. Retrieved 2009.