Benzenepropanal, b-phenyl-

Base Information

• Chemical Name: Benzenepropanal, b-phenyl-
• CAS No.: 4279-81-6
• Molecular Formula: C15H14O
• Molecular Weight: 210.276
• Hs Code.: 2912299000
• Mol file: 4279-81-6.mol

Synonyms:3-phenylcinnamyl alcohol;b-Phenylbenzenepropanal;3,3-diphenyl-1-propanal;3,3-diphenylprop-2-en-1ol;3,3-Diphenyl-propionaldehyd;3,3-diphenylallyl alcohol;3,3-Diphenyl-2-propen-1-ol;2-Propen-1-ol,3,3-diphenyl;3,3-diphenylpropionaldehyde;

Chemical Property of Benzenepropanal, b-phenyl-

Chemical Property:

• PSA: 17.07000
• LogP: 3.40750

Purity/Quality:

95% ^*data from raw suppliers

3,3-Diphenyl-propionaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenepropanal, b-phenyl-

There total 55 articles about Benzenepropanal, b-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

3,3-diphenylpropan-1-ol (20017-67-8) → 3,3-diphenylpropanal (4279-81-6)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 0 ℃; for 1.5h;

Reference yield: 93.0%

(E)-3-phenylpropenal (14371-10-9) + phenylboronic acid (98-80-6) → 3,3-diphenylpropanal (4279-81-6)

Guidance literature:

With acetic acid; [2,2]bipyridinyl; palladium diacetate; In tetrahydrofuran; water; at 40 ℃; for 72h;

DOI:10.1021/jo051561h

Reference yield: 92.0%

iodobenzene (591-50-4) + 3-phenyl-propenal (104-55-2) → 3,3-diphenyl-2-propenal (1210-39-5) + 3,3-diphenylpropanal (4279-81-6)

Guidance literature:

With formic acid; triethylamine; bis(triphenylphosphine) palladium (Il) acetate; In acetonitrile; at 80 ℃; for 6h;

DOI:10.1021/jo00171a016

upstream raw materials:

Diphenylmethane

chloroacetaldehyde diethyl acetal

(E)-3-phenylpropenal

iodobenzene

Downstream raw materials:

(3,3-dimethoxypropane-1,1-diyl)dibenzene

6-(2,2-diphenyl-ethyl)-1,2,6,7,8,9-hexahydro-furo[3,2-f]isoquinoline

4-(3,3-diphenyl-1-hydroxypropyl)-3-isopropoxy-5-(1-methoxycarbonyl-4-piperidyl)isothiazole

N, N-diisopropyl-3,3-diphenylpropan-1-amine

Refernces

• 1、 Wang, Yu,Zhang, Jian-Xin,Shu, Wei. "Cu-catalyzed remote transarylation of amines via unstrained C?C functionalization". . p. 15065 - 15070. Retrieved 2020.
• 2、 Motokura, Ken,Hashiguchi, Kohei,Maeda, Kyogo,Nambo, Masayuki,Manaka, Yuichi,Chun, Wang-Jae. "Rh-catalyzed 1,4-addition reactions of arylboronic acids accelerated by co-immobilized tertiary amine in silica mesopores". . p. 1 - 9. Retrieved 2019/05/04.