N-METHYLENEETHANAMINE

Base Information

• Chemical Name: N-METHYLENEETHANAMINE
• CAS No.: 43729-97-1
• Molecular Formula: C3H7N
• Molecular Weight: 57.0953
• Mol file: 43729-97-1.mol

Synonyms:Formaldehyd-aethylimin;CH3CH2N=CH2;N-ethyl methanaldimine;N-ethylmethyleneimine;N-Methylenethylamin;ethyl-methylen-amine;Ethanamine,N-methylene;N-METHYLENEETHANAMINE;N-methylideneethylamine;ethylmethyleneamine;

Chemical Property of N-METHYLENEETHANAMINE

Chemical Property:

• PSA: 12.36000
• LogP: 0.70690

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-METHYLENEETHANAMINE

There total 4 articles about N-METHYLENEETHANAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetraethyl-2-tetrazene (13304-29-5) → N,N-diethylnmethylamine (616-39-7) + N-methylideneethylamine (43729-97-1) + diethylamine (109-89-7) + 1,2-diethyl-1,2-diazetidine (66303-57-9)

Guidance literature:

at 350 - 500 ℃; under 0.0008 Torr; Product distribution; various temperatures of flash-vacuum pyrolisis; other alkyl-substituted substrates and their products;

Reference yield:

toluene (108-88-3,15644-74-3,16713-13-6) + diethylaminoacetonitrile (3010-02-4) → ethane (74-84-0) + ethene (74-85-1) + N-methylideneethylamine (43729-97-1) + N-(cyanomethyl)ethylamine (24426-40-2) + (N-ethyl-N-methyl)aminoacetonitrile (62842-25-5) + dihydrocinnamonitrile (645-59-0)

Guidance literature:

at 499.3 ℃; for 0.00012h; under 8.8 Torr; Product distribution; Thermodynamic data; Rate constant; var. temp., pressure, residence time, E_a, ΔS(excit.), ΔH(reaction), mechanism;

DOI:10.1002/kin.550270203

Reference yield:

N,N,N',N'-Tetraethylethylenediamine (150-77-6) → methane (34557-54-5,27936-85-2) + propane (74-98-6) + ethene (74-85-1) + N-methylideneethylamine (43729-97-1)

Guidance literature:

at 760 - 825 ℃; under 1E-05 Torr; Product distribution; photoelektron spectroscopy;

upstream raw materials:

N,N,N',N'-Tetraethylethylenediamine

tetraethyl-2-tetrazene

C₁₆H₁₈N

toluene

Downstream raw materials:

N-<(Nitrobenzoyloxy)methyl>-N-nitrosoethylamin

1,3,5-triethyl-1,3,5-triazacyclohexane

Refernces

• 1、 Martin, Gonzalo,Ascanio, Julian,Rodriguez, Jesus. "Gas Phase Thermolysis of Allyl Cyanomethyl Amine, Diallyl Cyanomethyl Amine, Diethyl Cyanomethyl Amine, and Diethyl Propargyl Amine". . p. 99 - 108. Retrieved 2007/10/02.
• 2、 Werstiuk, N. H.. "Thermolysis of N-alkylated ethylenediamines: an ultraviolet photoelectron spectroscopy study". . p. 2175 - 2183. Retrieved 2007/10/02.