2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl methacrylate

Base Information

• Chemical Name: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl methacrylate
• CAS No.: 3934-23-4
• Molecular Formula: C12H7 F15 O2
• Molecular Weight: 468.162
• Hs Code.: 29161900
• European Community (EC) Number: 223-509-1
• UNII: TG9Z8S9NYB
• DSSTox Substance ID: DTXSID5063235
• Nikkaji Number: J217.770F
• Wikidata: Q81985305
• Mol file: 3934-23-4.mol

Synonyms:3934-23-4;1h,1h-Perfluorooctyl methacrylate;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl methacrylate;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl 2-methylprop-2-enoate;Pentadecafluorooctyl methacrylate;1H,1H-PERFLUOROOCTYLMETHACRYLATE;2-Propenoic acid, 2-methyl-, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl ester;EINECS 223-509-1;1h,1h-pentadecafluorooctyl methacrylate;TG9Z8S9NYB;SCHEMBL36922;DTXSID5063235;C12H7F15O2;(perfluoroheptyl)methyl methacrylate;MFCD00039247;1,1-dihydroperfluorooctyl methacrylate;AKOS025310205;C12-H7-F15-O2;Methacrylic acid 1H,1H-perfluorooctyl ester;CS-0212371;FT-0609065;1H,1H-Perfluorooctyl methacrylate, contains MEHQ as inhibitor, 96%;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl 2-methyl-2-propenoate;Methacrylic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl ester

Chemical Property of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl methacrylate

Chemical Property:

• Vapor Pressure: 0.057mmHg at 25°C
• Refractive Index: 1.337
• Boiling Point: 219.8 °C at 760 mmHg
• Flash Point: 84.5 °C
• PSA: 26.30000
• Density: 1.524 g/cm³
• LogP: 5.47980
• Storage Temp.: Keep Cold
• XLogP3: 6.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 17
• Rotatable Bond Count: 9
• Exact Mass: 468.0206519
• Heavy Atom Count: 29
• Complexity: 646

Purity/Quality:

99.3% ^*data from raw suppliers

1H,1H-Perfluoro-n-octyl methacrylate 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 36/37/38-22
• Safety Statements: 26-36/37/39-28-24/25-23

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl methacrylate

There total 3 articles about 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol (307-30-2) + Methacryloyl chloride (920-46-7,26937-45-1) → 1,1-dihydroperfluorooctyl methacrylate (3934-23-4)

Guidance literature:

With triethylamine; In tetrahydrofuran; Yield given;

DOI:10.1039/a705399a

Reference yield:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol (307-30-2) + poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) → 1,1-dihydroperfluorooctyl methacrylate (3934-23-4)

Guidance literature:

With sulfuric acid; hydroquinone; In benzene; Heating;

DOI:10.1016/S0022-1139(00)85059-9

Reference yield:

→ 1,1-dihydroperfluorooctyl methacrylate (3934-23-4)

Guidance literature:

upstream raw materials:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

poly(methacrylic acid)

Methacryloyl chloride

Refernces

• 1、 Yong, Tuck-Mun,Hems, William P.,Van Nunen, Johanna L. M.,Holmes, Andrew B.,Steinke, Joachim H. G.,Taylor, Philip L.,Segal, John A.,Griffin, David A.. "Synthesis of fluorinated block copolymers and their application as novel polymerisation surfactants in supercritical carbon dioxide". . p. 1811 - 1812. Retrieved 2007/10/03.