1H,1H-Pentadecafluoro-1-octanol

Base Information

• Chemical Name: 1H,1H-Pentadecafluoro-1-octanol
• CAS No.: 307-30-2
• Molecular Formula: C8H3 F15 O
• Molecular Weight: 400.087
• Hs Code.: 29055900
• European Community (EC) Number: 206-197-1
• UNII: 9X5W7FQ62R
• DSSTox Substance ID: DTXSID5059793
• Nikkaji Number: J193.718I
• Wikidata: Q27273340
• Mol file: 307-30-2.mol

Synonyms:1H,1H-Pentadecafluoro-1-octanol;307-30-2;1H,1H-Perfluoro-1-octanol;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol;(perfluoroheptyl)methanol;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-1-octanol;Pentadecafluorooctyl alcohol;1h,1h-perfluorooctan-1-ol;C8H3F15O;1-Octanol, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-;1h,1h-perfluorooctanol;7:1 Fluorotelomer alcohol;UNII-9X5W7FQ62R;(pentadecafluoroheptyl)methanol;9X5W7FQ62R;EINECS 206-197-1;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl alcohol;Pentadecafluoroheptylmethanol;1,1-dihydroperfluorooctanol;C7F15CH2OH;1H,1H-Pentadecafluorooctanol;Pentadecafluorocaprylic alcohol;SCHEMBL152122;1H,1H-Pentadecafluorooctanol-1;DTXSID5059793;1h,1h-pentadecafluorooctan-1-ol;Caprylic alcohol, pentadecafluoro-;C8-H3-F15-O;1H,1H-Perfluoro-1-octanol, 97%;MFCD00004675;AKOS015912511;1,1-DIHYDROPENTADECAFLUOROOCTANOL;AS-75537;PENTADECAFLUORO-1,1-DIHYDROOCTANOL;1,1-DIHYDROPENTADECAFLUOROOCTAN-1-OL;CS-0121605;FT-0606123;P0904;.ALPHA.,.ALPHA.-DIHYDROPERFLUOROOCTANOL;D92038;Q27273340;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctan-l-ol;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-1-octanol, 98%

Chemical Property of 1H,1H-Pentadecafluoro-1-octanol

Chemical Property:

• Appearance/Colour: white crystalline mass
• Vapor Pressure: 0.681mmHg at 25°C
• Melting Point: 44-47 °C(lit.)
• Refractive Index: 1.3084
• Boiling Point: 163-165 °C(lit.)
• PKA: 12.86±0.10(Predicted)
• Flash Point: >110°C
• PSA: 20.23000
• Density: 1,338 g/cm³
• LogP: 4.35280
• Solubility.: almost transparency in Methanol
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 16
• Rotatable Bond Count: 6
• Exact Mass: 399.9944371
• Heavy Atom Count: 24
• Complexity: 461

Purity/Quality:

98%,99%, ^*data from raw suppliers

1H,1H-Pentadecafluoro-1-octanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)O

Technology Process of 1H,1H-Pentadecafluoro-1-octanol

There total 8 articles about 1H,1H-Pentadecafluoro-1-octanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

isopropyl 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate (106608-82-6) → 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol (307-30-2)

Guidance literature:

With RuCl2(DPPEA)(±DAIPEN); hydrogen; sodium methylate; In isopropyl alcohol; benzene; at 100 ℃; for 40h; under 750.075 - 45004.5 Torr; Autoclave;

Reference yield: 77.0%

pentadecafluorooctanoyl chloride (335-64-8) → 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol (307-30-2)

Guidance literature:

With sodium bis(2-methoxyethoxy)aluminium dihydride; In diethyl ether; toluene; for 0.5h; Heating;

DOI:10.1016/S0022-1139(00)80195-5

Reference yield:

Perfluorooctanoic acid (335-67-1) → 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol (307-30-2)

Guidance literature:

With diethyl ether; pyrographite; ruthenium; at 175 ℃; under 257428 Torr; Hydrogenation;

upstream raw materials:

pentadecafluorooctanoyl chloride

Perfluorooctanoic acid

pentadecafluoro-octanoic acid butyl ester

ethyl perfluorooctanoate

Downstream raw materials:

1H,1H-perfluoro-n-octyl acrylate

1H,1H-pentadecafluorooctyl allyl ether

1,3-Dinitro-2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-octyloxy)-5-trifluoromethyl-benzene

1,1-dihydroperfluorooctyl methacrylate

Refernces

• 1、 -. "A process for the preparation of the fluoro method". . . Retrieved 2017/06/29.
• 2、 Tung, Chen-Ho,Ji, Hai-Feng. "Aggregation Behavior of Mixed Fluorocarbon and Hydrocarbon Molecules in Aqueous Organic Solvents. Nonideality and Ideality of Mixing". . p. 8311 - 8316. Retrieved 2007/10/02.