Phosphoric acid, monomethyl ester, ion(1-)

Base Information

• Chemical Name: Phosphoric acid, monomethyl ester, ion(1-)
• CAS No.: 48000-95-9
• Molecular Formula: CH4O4P
• Molecular Weight: 111.014
• Mol file: 48000-95-9.mol

Synonyms:

Chemical Property of Phosphoric acid, monomethyl ester, ion(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphoric acid, monomethyl ester, ion(1-)

There total 11 articles about Phosphoric acid, monomethyl ester, ion(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + tetra-n-butylammonium 4-nitrophenyl hydrogen phosphate (75089-59-7) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + Methyl phosphate anion (48000-95-9) + CH4O7P2(2-)

Guidance literature:

In [D₃]acetonitrile; at 70 ℃; solvolysis; investigation of half times of reaction by 31P NMR; various solvents and reagents;

DOI:10.1016/0040-4020(80)80159-1

Reference yield:

methanol (67-56-1) + bis-tetra-n-butylammonium 4-nitrophenyl phosphate (75089-59-7,75089-60-0) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + Methyl phosphate anion (48000-95-9)

Guidance literature:

With water; In [D₃]acetonitrile; at 35 ℃; solvolysis; investigation of half-times of reaction by 31P NMR; various solvents and reagents;

DOI:10.1016/0040-4020(80)80159-1

Reference yield:

N-butylamine (109-73-9,85404-21-3) + benzoyl methyl phosphate → N-butylbenzamide (2782-40-3) + Methyl phosphate anion (48000-95-9)

Guidance literature:

With potassium chloride; In water; at 25 ℃; Kinetics;

DOI:10.1021/jo800667b

upstream raw materials:

methanol

tetra-n-butylammonium phenyl hydrogen phosphate

tetrabutyl-ammonium monophenyl phosphate

tetra-n-butylammonium 4-nitrophenyl hydrogen phosphate

Refernces

• 1、 Ramirez, Fausto,Marecek, James F.. "PHOSPHORYL TRANSFER FROM PHENYL AND 4-NITROPHENYL PHOSPHATES IN APROTIC AND PROTIC SOLVENTS. AMINE CATALYSIS AND FORMATION OF OXYPHOSPHORANE AND METAPHOSPHATE INTERMEDIATES". . p. 3151 - 3160. Retrieved 2007/10/02.