(α-Hydroxybenzhydryl)radical

Base Information

• Chemical Name: (α-Hydroxybenzhydryl)radical
• CAS No.: 4971-41-9
• Molecular Formula: C13H11O
• Molecular Weight: 183.23
• Mol file: 4971-41-9.mol

Synonyms:α-hydroxydiphenylmethyl radical;diphenylhydroxylmethyl radical;diphenylmethanol radical;

Chemical Property of (α-Hydroxybenzhydryl)radical

Chemical Property:

• PSA: 20.23000
• LogP: 2.42930

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (α-Hydroxybenzhydryl)radical

There total 67 articles about (α-Hydroxybenzhydryl)radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1-Diphenylmethanol (91-01-0) + benzyloxyl (26397-37-5) → hydroxy-diphenyl-methyl (4971-41-9) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

In benzene; at 27 ℃; Rate constant; Irradiation;

DOI:10.1021/ja00383a019

Reference yield:

benzophenone (119-61-9) + α-hydroxybenzyl radical (2406-15-7) → hydroxy-diphenyl-methyl (4971-41-9) + benzaldehyde (100-52-7)

Guidance literature:

Thermodynamic data; Mechanism; ΔE(excit.), ΔH, other ketyl radicals, other carbonyl compounds;

DOI:10.1007/BF02494263

Reference yield:

1,1-Diphenylmethanol (91-01-0) + 2-phenylehoxy radical (40355-55-3) → 2-phenylethanol (60-12-8) + hydroxy-diphenyl-methyl (4971-41-9)

Guidance literature:

In benzene; at 27 ℃; Rate constant; Irradiation;

DOI:10.1021/ja00383a019

upstream raw materials:

benzophenone

SEC-BUTYLAMINE

9,9-dideuterio-N-methylacridan

1,1-Diphenylmethanol

Downstream raw materials:

benzophenone

methyl diphenylmethyl radical

isopropyl radical

sec-Butyl-Radikal

Refernces

• 1、 Roberts, Christopher B.,Chateauneuf, John E.,Brennecke, Joan F.. "Unique Pressure Effects on the Absolute Kinetics of Triplet Benzophenone Photoreduction in Supercritical CO2". . p. 8455 - 8463. Retrieved 1992.
• 2、 Bensasson, Rene V.,Gramain, Jean-Claude. "Benzophenone Triplet Properties in Acetonitrile and Water". . p. 1801 - 1810. Retrieved 1980.
• 3、 Michael Bookman,Hubig, Stephan M.,Kochi, Jay K.. "Direct observation of carbon - Carbon bond cleavage in ultrafast decarboxylations". . p. 4502 - 4503. Retrieved 1996.
• 4、 Wakasa, Masanobu,Hayashi, Hisaharu. "Magnetic Field Effects on the Hydrogen Abstraction Reactions of Triplet Benzophenone with Thiophenol in Nonviscous Homogenous Solutions". . p. 15640 - 15643. Retrieved 1996.
• 5、 Borisevich, N. A.,Lysak, N. A.,Mel'nichuk, S. V.,Tikhomirov, S. A.,Tolstorozhev, G. B.. "INFLUENCE OF DONOR HYDROGEN AND THE POLARITY OF THE MEDIUM ON THE MECHANISM OF FORMATION OF THE KETYL RADICAL". . p. 1077 - 1081. Retrieved 1988.
• 6、 Inbar, Shai,Linschitz, Henry,Cohen, Saul G.. "Nanosecond Flash Studies of Reduction of Benzophenone by Aliphatic Amines. Quantum Yields and Kinetic Isotope Effects". . p. 1048 - 1054. Retrieved 1981.
• 7、 Hamatani, Satoshi,Tsuji, Kazuhide,Kawai, Akio,Shibuya, Kazuhiko. "Dispersed fluorescence spectra of jet-cooled benzophenone ketyl radical: Assignment of the low-frequency vibrational modes". . p. 1370 - 1375. Retrieved 2003.
• 8、 Khan, Jamal,Casey, David,Linschitz, Henry,Cohen, Saul G.. "Reaction of Triplet Benzophenone with Hydroxylamines: Yields of Radicals and Kinetics of Their Formation and Decay". . p. 6080 - 6083. Retrieved 1991.
• 9、 Sakamoto, Masanori,Cai, Xichen,Fujitsuka, Mamoru,Majima, Tetsuro. "Properties of excited ketyl radicals of benzophenone analogues affected by the size and electronic character of the aromatic ring systems". . p. 1610 - 1617. Retrieved 2006.
• 10、 Chandrasekaran, K.,Whitten, David G.. "Applications of Light-Induced Electron Transfer and Hydrogen-Abstraction Processes: Photoelectrochemical Production of Hydrogen from Reducing Radicals". . p. 5119 - 5120. Retrieved 1980.