4-Bromo-4'-(bromomethyl)-1,1'-biphenyl

Base Information Edit

Chemical Name:4-Bromo-4'-(bromomethyl)-1,1'-biphenyl
CAS No.:50670-57-0
Molecular Formula:C₁₃H₁₀Br₂
Molecular Weight:326.03
Hs Code.:
DSSTox Substance ID:DTXSID30602879
Wikidata:Q82500080
Mol file:50670-57-0.mol

Synonyms:50670-57-0;4-Bromo-4'-(bromomethyl)-1,1'-biphenyl;4'-BROMO-4-BROMOMETHYL-BIPHENYL;4-BROMO-4-BROMOMETHYL-BIPHENYL;1-bromo-4-[4-(bromomethyl)phenyl]benzene;1,1'-Biphenyl, 4-bromo-4'-(bromomethyl)-;SCHEMBL3362246;4-Bromomethyl-4'-Bromobiphenyl;DTXSID30602879;AJHADXHEAFCOTE-UHFFFAOYSA-N;MFCD15523810;AKOS024257895;AS-60066;SY344892;4-Bromo-4 inverted exclamation mark -(bromomethyl)-1,1 inverted exclamation mark -biphenyl

Suppliers and Price of 4-Bromo-4'-(bromomethyl)-1,1'-biphenyl

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
4-Bromo-4'-(bromomethyl)-1,1'-biphenyl 97%
10g
$ 1650.00

Crysdot
4-Bromo-4'-(bromomethyl)-1,1'-biphenyl 97%
5g
$ 980.00

Alichem
4-Bromo-4'-(bromomethyl)-1,1'-biphenyl
10g
$ 1749.00

Alichem
4-Bromo-4'-(bromomethyl)-1,1'-biphenyl
5g
$ 989.80

Total 3 raw suppliers

Chemical Property of 4-Bromo-4'-(bromomethyl)-1,1'-biphenyl Edit

Chemical Property:

PSA：0.00000
LogP:5.01100
XLogP3:5.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:325.91288
Heavy Atom Count:15
Complexity:177

Purity/Quality:

95% ^*data from raw suppliers

4-Bromo-4'-(bromomethyl)-1,1'-biphenyl 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=CC=C1CBr)C2=CC=C(C=C2)Br

Technology Process of 4-Bromo-4'-(bromomethyl)-1,1'-biphenyl

There total 8 articles about 4-Bromo-4'-(bromomethyl)-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 84337-86-0
<4-(4-bromophenyl)phenyl>methanol

: 50670-57-0
4-bromo-4'-(bromomethyl)-1,1'-biphenyl

Guidance literature:: With dibromotriphenylphosphorane; In dichloromethane; at 20 ℃; for 2h;

Reference yield:

: 50670-49-0
4-bromo-4'-methylbiphenyl

: 50670-57-0
4-bromo-4'-(bromomethyl)-1,1'-biphenyl

Guidance literature:: With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 0.25h; Heating;
DOI:10.1021/jm00377a022

Reference yield:

: 619-44-3
methyl 4-iodobenzoate

: 50670-57-0
4-bromo-4'-(bromomethyl)-1,1'-biphenyl

Guidance literature:: Multi-step reaction with 3 steps

1: sodium carbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / ethanol; water; toluene / 4 h / 80 °C

2: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 °C

3: dibromotriphenylphosphorane / dichloromethane / 2 h / 20 °C

With lithium aluminium tetrahydride; sodium carbonate; dibromotriphenylphosphorane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; ethanol; dichloromethane; water; toluene; 1: Suzuki Coupling;