Trihydride(methylaminio) boronanion

Base Information

• Chemical Name: Trihydride(methylaminio) boronanion
• CAS No.: 1722-33-4
• Molecular Formula: CH8 B N
• Molecular Weight: 44.8922
• Nikkaji Number: J3.237.893E
• Mol file: 1722-33-4.mol

Synonyms:Trihydride(methylaminio) boronanion

Chemical Property of Trihydride(methylaminio) boronanion

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 45.0749794
• Heavy Atom Count: 3
• Complexity: 4.8

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [BH3-][NH2+]C

Technology Process of Trihydride(methylaminio) boronanion

There total 10 articles about Trihydride(methylaminio) boronanion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 6.0%

dimethylamine borane (74-94-2) → methylamine-borane (1722-33-4) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine; trimethylsilyl trifluoromethanesulfonate; In 1,2-dichloro-benzene; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/ejic.201000515

Reference yield:

Me3N-BH2-NHMe-BH3 (1349095-84-6) → (methylamino)dihydroborane (6601-31-6) + methylamine-borane (1722-33-4) + trimethylamine-borane (75-22-9) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

In tetrahydrofuran; at 70°C for 16 h;

DOI:10.1021/ja208752w

Reference yield:

Me3N-BH2-NHMe-BH3 (1349095-84-6) → methylamine-borane (1722-33-4) + trimethylamine-borane (75-22-9) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

In tetrahydrofuran; at 70 ℃; for 16h; Inert atmosphere;

DOI:10.1021/ja208752w

upstream raw materials:

dimethylamine borane

MeNH₂-BH₂-NHMe-BH₃

Me₃N-BH₂-NHMe-BH₃

diisopropopylaminoborane

Downstream raw materials:

hydrogen

boric acid

methylamine

methylammonium cation

Refernces

• 1、 Robertson, Alasdair P. M.,Leitao, Erin M.,Manners, Ian. "Catalytic redistribution and polymerization of diborazanes: Unexpected observation of metal-free hydrogen transfer between aminoboranes and amine-boranes". supporting information; experimental part. p. 19322 - 19325. Retrieved 2012/01/13.