Titanium(4+);tetraiodide

Base Information

• Chemical Name: Titanium(4+);tetraiodide
• CAS No.: 7720-83-4
• Molecular Formula: I4Ti
• Molecular Weight: 555.498
• Hs Code.: 28276000
• Nikkaji Number: J95.269I
• Mol file: 7720-83-4.mol

Synonyms:AKOS025295734

Chemical Property of Titanium(4+);tetraiodide

Chemical Property:

• Appearance/Colour: purple to black fused solid
• Melting Point: 150-151 °C
• Boiling Point: 377.1 °C at 760 mmHg
• PSA: 0.00000
• Density: 4.3 g/cm³
• LogP: 3.54280
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in dichloromethane, chloroform, carbon disulfide.
• Water Solubility.: dissolves and hydrolyzes in H2O [KIR82]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 555.5658
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Titanium(IV) iodide (99.99%-Ti) PURATREM ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-37
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Ti+4].[I-].[I-].[I-].[I-]
• Uses: Titanium(IV) iodide, anhydrous is used in the CVD of titanium nitride films with optimized characteristics.

Technology Process of Titanium(4+);tetraiodide

There total 20 articles about Titanium(4+);tetraiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

selenium (7782-49-2) + titanium (7440-32-6) + iodine (7553-56-2,12190-71-5,8031-47-8) → Ti4Se8.2I5.2 + titanium(IV) iodide (7720-83-4)

Guidance literature:

In neat (no solvent); at 250 ℃; for 202h; Sealed tube;

DOI:10.1016/j.ica.2019.01.037

Reference yield:

titanium tetrachloride (7550-45-0) + potassium iodide (7681-11-0) → titanium(IV) iodide (7720-83-4)

Guidance literature:

Reference yield:

titanium (7440-32-6) → titanium(IV) iodide (7720-83-4)

Guidance literature:

With iodine; at 360 °C;

upstream raw materials:

titanium tetrachloride

potassium iodide

titanium

hydrogen iodide

Downstream raw materials:

phosphorous triiodide

titanium tetrachloride

germanium tetraiodide

iodine

Refernces

• 1、 Blocher, J. M.,Campbell, I. E.. "". . p. 2100 - 2101. Retrieved 1947.
• 2、 Cartwright, Michael,Woolf, Alfred A.. "". . . Retrieved 1976.
• 3、 Denes Georges. "'Bent copper tube': A new inexpensive and convenient reactor for fluorides of metals in suboxidation states". . p. 54 - 59. Retrieved 2008/10/08.