POTASSIUM PERRUTHENATE

Base Information

• Chemical Name: POTASSIUM PERRUTHENATE
• CAS No.: 10378-50-4
• Molecular Formula: K*O₄Ru
• Molecular Weight: 204.166
• Hs Code.: 28439090
• Mol file: 10378-50-4.mol

Synonyms:Perruthenicacid (HRuO4), potassium salt (8CI); Potassium ruthenate(VII) (7CI); Ruthenate(RuO41-), potassium, (T-4)- (9CI); Potassium perruthenate; Potassium ruthenate(KRuO4); Potassium ruthenium oxide (KRuO4); Potassium ruthenium tetraoxide

Chemical Property of POTASSIUM PERRUTHENATE

Chemical Property:

• Appearance/Colour: Black crystals
• Melting Point: 44 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 74.27000
• Density: g/cm³
• LogP: -0.47520
• Solubility.: H2O: slightly soluble(lit.)
• Water Solubility.: Slightly soluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Potassium perruthenate, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): OXi
• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Potassium perruthenate(VII) is used in the production of carbon nanotubes for flexible solid-state supercapacitors. It is also used as an oxidizing agent in the synthesis of 5-formylcytosine from 5-hydroxymethylcytosine.

Technology Process of POTASSIUM PERRUTHENATE

There total 7 articles about POTASSIUM PERRUTHENATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ruthenium tetroxide (20427-56-9) + potassium ruthenate + potassium hydroxide → potassium perrhuthenate (10378-50-4)

Guidance literature:

In water; distg. RuO4 in an aq. soln. of K2RuO4 contg. KOH; pptn. after cooling for a few days;; washing with ice-water;;

DOI:10.1021/ja01641a072

Reference yield:

potassium ruthenate * water → potassium perrhuthenate (10378-50-4)

Guidance literature:

With carbon dioxide; chlorine; In water; concd. soln.;;

Reference yield:

potassium ruthenate → potassium perrhuthenate (10378-50-4)

Guidance literature:

In not given; diln.;

upstream raw materials:

ruthenium trichloride hydrate

ruthenium tetroxide

ruthenium

potassium hydrogensulfate

Refernces

• 1、 Silverman, M. D.,Levy, H. A.. "". . p. 3317 - 3319. Retrieved 1954.