Ruthenium(III) chloride hydrate

Base Information

• Chemical Name: Ruthenium(III) chloride hydrate
• CAS No.: 14898-67-0
• Molecular Formula: RuCl3.xH2O
• Molecular Weight: 207.42900
• Hs Code.: 2843 90 90
• European Community (EC) Number: 604-667-4
• Mol file: 14898-67-0.mol

Synonyms:Ruthenium(III) chloride hydrate;20759-14-2;ruthenium trichloride hydrate;trichlororuthenium;hydrate;Ruthenium(III)ChlorideHydrate;ruthenium choride hydrate;ruthenium chloride hydrate;MFCD00149844;Ruthenium trichoride hydrate;ruthenium chloride n hydrate;Ruthenium(III)chloride hydrate;ruthenium (iii) chloride hydrate;ruthenium (III) chloride-hydrate;Ruthenium(III) chloride xhydrate;ruthenium(III) trichloride hydrate;ruthenium(III)-trichloride hydrate;ruthenium trichloride monohydrate;H2Cl3ORu;ruthenium chloride, hydrous;ruthenium chloride n-hydrate;ruthenium trichloride, hydrate;ruthenium(+3)chloride hydrate;Ruthenium chloride (RuCl3), monohydrate (8CI,9CI);ruthenium-(iii)-chloride hydrate;ruthenium(iii) chloride n-hydrate;BIXNGBXQRRXPLM-UHFFFAOYSA-K;Ruthenium(III)chloridehydrate(1:x);ruthenium (III) chloride monohydrate;AKOS015855144;CS-O-02285;SY003262;Ruthenium(III) chloride hydrate, Premion?;CS-0031493;Ruthenium(III) chloride hydrate, ReagentPlus(R);Ruthenium(III) chloride hydrate, 38.0-42.0% Ru basis;Ruthenium(III) chloride hydrate (38-43% Ru) (99.9%-Ru);Ruthenium(III) chloride hydrate, >=99.95% Trace metals grade;Ruthenium(III) chloride hydrate, 99.98% trace metals basis;Ruthenium(III) chloride hydrate (40-43% Ru) (99.99+%-Ru) [free of Ru(II) and Ru(IV) by electrochemical analysis]

Chemical Property of Ruthenium(III) chloride hydrate

Chemical Property:

• Appearance/Colour: powder
• Melting Point: >300°C
• PSA: 0.00000
• Density: 3.11 g/cm3
• LogP: -8.98800
• Storage Temp.: Store at +5°C to +30°C.
• Sensitive.: Hygroscopic
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 224.821463
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

Ru 37% ^*data from raw suppliers

Ruthenium(III)ChlorideHydrate(TechnicalGrade) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R22:; R34:; R52/53:
• Hazard Codes: C
• Statements: 34-52/53-22
• Safety Statements: 26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O.Cl[Ru](Cl)Cl
• Uses: Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1 Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs? catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

Technology Process of Ruthenium(III) chloride hydrate

There total 5 articles about Ruthenium(III) chloride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

water (7732-18-5) + ruthenium(III)chloride (10049-08-8,63767-78-2) → ruthenium(III) chloride hydrate (20759-14-2,14898-67-0)

Guidance literature:

With HCl; In hydrogenchloride; Electrolysis; soln. of RuCl3 in 2n HCl is electrolysed as catholyte; subsequent concn. of the red soln. in HCl-stream under exclusion of air first at the b.p., later at 80-100°C to dryness;; drying over concd. H2SO4 in vacuum leads to a product free from Ru(IV);;

Reference yield:

ruthenium(IV) hydroxide (12181-34-9) → ruthenium(III) chloride hydrate (20759-14-2,14898-67-0)

Guidance literature:

With hydrogenchloride; In hydrogenchloride; dissolving Ru(OH)4 in HCl (100°C), addn. of H2C2O4; according to Shorikov, Yu. S., et al., Zh. Neorg. Khim., 1984, 29(12), 2999; (Russ. J. Inorg. Chem., 1984(12)); evapn., drying (vac. over alkali, room temp.); elem. anal.;

Reference yield:

ruthenium trichloride hydrate (14898-67-0) + water (7732-18-5) → ruthenium(III) chloride trihydrate (14898-67-0)

Guidance literature:

In hydrogenchloride; Ru salt treated several times with HCl soln.;

DOI:10.1021/ic801748t

upstream raw materials:

water

ruthenium(III)chloride

ruthenium(IV) hydroxide

Downstream raw materials:

trans-3-oxospiro[isobenzofuran-1(3H),1'-cyclohexane]-4'-carboxylic acid

(η(5)-C5H5)RuCl(P(p-CF3C6H4)3)2

[(η5-C5H5)Ru(P(3-CH3-C6H4)3)2Cl]

{RuBr₂(CO)2(C₆H₅NH₂)2}

Refernces

• 1、 Zahmakiran, Mehmet,Tonbul, Yalcin,Oezkar, Saim. "Ruthenium(0) nanoclusters stabilized by a nanozeolite framework: Isolable, reusable, and green catalyst for the hydrogenation of neat aromatics under mild conditions with the unprecedented catalytic activity and lifetime". . p. 6541 - 6549. Retrieved 2010.