Ruthenium chloride (RuCl3)

Base Information

• Chemical Name: Ruthenium chloride (RuCl3)
• CAS No.: 10049-08-8
• Molecular Formula: RuCl3
• Molecular Weight: 207.429
• Hs Code.: 28439000
• UNII: RY8V1UJV23
• Nikkaji Number: J96.378J
• Mol file: 10049-08-8.mol

Synonyms:ruthenium chloride;ruthenium chloride (RuCl2), 103Ru-labeled;ruthenium chloride (RuCl3);ruthenium chloride (RuCl3), 103Ru-labeled;ruthenium chloride (RuCl3), 106Ru-labeled;ruthenium chloride (RuCl4), 103Ru-labeled;ruthenium chloride trihydrate;ruthenium trichloride

Chemical Property of Ruthenium chloride (RuCl3)

Chemical Property:

• Appearance/Colour: Dark red solution
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 500 °C
• PSA: 0.00000
• Density: 3.11 g/mL at 25 °C(lit.)
• LogP: -8.98800
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Hygroscopic
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 206.810898
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Ruthenium(III) Chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-52/53-22
• Safety Statements: 26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Ru+3]
• Uses: Ruthenium(III) chloride is widely used as a starting material of ruthenium complexes. It acts as a catalyst used in the oxidative cyclization of 1,7-dienes to oxepane diols. It is used in the hydroxylation of tertiary hydrocarbons in combination of periodate or bromate. It is involved as a catalyst in the synthesis of 2,3-pyridinedicarboxylic acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis. Analysis (testing for sulfur trioxide).Ruthenium trichloride is by far the best starting material for the synthesis of compounds of the metal. Like osmium, ruthenium exhibits a wide range of oxidation states in its complexes (VIII to —II), and all of these may be reached from RuCl3 since, although it is stable, it can easily be oxidised or reduced. It is most commonly used in the hydrated form, this being soluble in many solvents, but for anhydrous or solid-state reactions β-RuCl3 is the best source. Ruthenium(III) trichloride is used for technical analysis in chemistry laboratories. It is highly toxic.Ruthenium(III) chloride is a catalyst that is used in the synthesis of 2,3-Pyridinedicarboxylic Acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis.

Technology Process of Ruthenium chloride (RuCl3)

There total 35 articles about Ruthenium chloride (RuCl3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

ruthenium(IV) chloride (13465-52-6) → hydrogenchloride (7647-01-0,15364-23-5) + Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl + ruthenium(III)chloride (10049-08-8,63767-78-2)

Guidance literature:

With water; In water; byproducts: Cl2; Cl2 removed by CO2 before hydrolysis completed;;

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) → ruthenium(III)chloride (10049-08-8,63767-78-2)

Guidance literature:

In neat (no solvent); 140°C, 48 h;

DOI:10.1021/ja973938+

Reference yield:

chlorine (7782-50-5) + ruthenium (7440-18-8) → ruthenium(III)chloride (10049-08-8,63767-78-2)

Guidance literature:

In neat (no solvent); finely dispersed Ru;;

upstream raw materials:

ruthenium(IV) chloride

ruthenium(III) chloride trihydrate

H⁽¹⁺⁾*{Ru(H₂O)2Cl₄}^(1-)=H{Ru(H₂O)2Cl₄}

H⁽¹⁺⁾*{Ru(H₂O)2Cl₄}^(1-)=H{Ru(H₂O)2Cl₄}

Downstream raw materials:

Cs⁽¹⁺⁾*{RuCl₃(CO)3}^(1-)=Cs{RuCl₃(CO)3}

{Ru(N₃)2(C₂₆H₂₄P₂)2}

ruthenium

bis(η⁵-cyclopentadienyl)ruthenium

Refernces

• 1、 Wang, Lei,Rocci-Lane, Melissa,Brazis, Paul,Kannewurf, Carl R.,Kim, Young-Il,Lee, Woo,Choy, Jin-Ho,Kanatzidis, Mercouri G.. "α-RuCl3/polymer nanocomposites: The first group of intercalative nanocomposites with transition metal halides". . p. 6629 - 6640. Retrieved 2000.
• 2、 Cordfunke, E. H. P.,Konings, R. J. M.. "". . p. 63 - 70. Retrieved 1988.
• 3、 Fletcher, J. M.,Gardner, W. E.,Hooper, E. W.,Hyde, K. R.,Moore, F. H.,Woodhead, J. L.. "". . p. 1089 - 1090. Retrieved 1963.
• 4、 -. "Process for production of bis (alkyl cyclopentadienyl) ruthenium and bis (alkyl cyclopentadienyl) ruthenium produced by the process". . . Retrieved 2008/06/13.