(2-hydroxyphenyl)diphenylphosphine

Base Information

• Chemical Name: (2-hydroxyphenyl)diphenylphosphine
• CAS No.: 60254-10-6
• Molecular Formula: C18H15OP
• Molecular Weight: 278.29
• Hs Code.: 2907199090
• Mol file: 60254-10-6.mol

Synonyms:Phenol,2-(diphenylphosphino);2-(Diphenylphosphino)phenol;(o-Diphenylphosphino)phenol;o-hydroxyphenyl-diphenylphosphane;OHC6H4PPh2-o;diphenyl-(o-hydroxyphenyl)-phosphine;(2-hydroxyphenyl)diphenyl phosphine;(o-Hydroxyphenol)diphenylphosphine;

Chemical Property of (2-hydroxyphenyl)diphenylphosphine

Chemical Property:

• Melting Point: 142-150°C
• Boiling Point: 395.1±25.0 °C(Predicted)
• PKA: 9.33±0.30(Predicted)
• PSA: 33.82000
• LogP: 3.15040
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

(2-Hydroxyphenyl)diphenylphosphine, 97% 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Catalyst for:Preparation of hydroxy(phosphinoxy)biphenylsFormation of ethylene copolymersCopolymerization of ethylene with linear olefinsSilylation of aryl halides

Technology Process of (2-hydroxyphenyl)diphenylphosphine

There total 20 articles about (2-hydroxyphenyl)diphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(2-Hydroxyphenyl)diphenylphosphane hydrobromid → (o-hydroxyphenyl)diphenylphosphine (60254-10-6)

Guidance literature:

With sodium; In ethanol; for 5h; Ambient temperature;

Reference yield: 88.0%

[2-(1-ethoxy-ethoxy)-phenyl]-diphenyl-phosphane → (o-hydroxyphenyl)diphenylphosphine (60254-10-6)

Guidance literature:

With pyridinium p-toluenesulfonate; In ethanol; dichloromethane; at 65 ℃; for 4h;

DOI:10.1021/ja046901f

Reference yield: 83.0%

2-Iodophenol (533-58-4) + diphenylphosphane (829-85-6) → (o-hydroxyphenyl)diphenylphosphine (60254-10-6)

Guidance literature:

With sodium acetate; palladium diacetate; In N,N-dimethyl acetamide; at 110 ℃; for 17h; Inert atmosphere;

DOI:10.1002/cssc.202002267

upstream raw materials:

2-hydroxyphenyltriphenylphosphonium chloride

2-Iodophenol

diphenylphosphane

(2-methoxyphenyl)diphenylphosphine

Downstream raw materials:

4,8-di-tert-butyl-6-(2-diphenylphosphanyl-phenoxy)-1,2,10,11-tetramethyl-5,7-dioxa-6-phospha-dibenzo[a,c]cycloheptene

N-benzyloxycarbonyl-L-aspartic acid 4-(2-diphenylphosphanyl-phenyl) ester 1-methyl ester

(2-(diphenylphosphino)phenolato)(2-mercaptobenzoyl)bis(trimethylphosphine)cobalt(III)

2-(diphenylphosphanyl)phenyl 4-iodobenzoate

Refernces

• 1、 Hu, Yuya,Wei, Zhihong,Frey, Anna,Kubis, Christoph,Ren, Chang-Yue,Spannenberg, Anke,Jiao, Haijun,Werner, Thomas. "Catalytic, Kinetic, and Mechanistic Insights into the Fixation of CO2 with Epoxides Catalyzed by Phenol-Functionalized Phosphonium Salts". . p. 363 - 372. Retrieved 2020/11/30.
• 2、 Fischer, Malte,Schaper, Raoul,Jaugstetter, Maximilian,Schmidtmann, Marc,Beckhaus, Rüdiger. "Electrophilic d0 Cations of Group 4 Metals (M = Ti, Zr, Hf) Derived from Monopentafulvene Complexes: Direct Formation of Tridentate Cp, O, P -Ligands". supporting information. p. 1192 - 1205. Retrieved 2018/04/17.