Diphenyl(trimethylsilyl)phosphine

Base Information

• Chemical Name: Diphenyl(trimethylsilyl)phosphine
• CAS No.: 17154-34-6
• Molecular Formula: C15H19 P Si
• Molecular Weight: 258.375
• Hs Code.: 29319090
• Mol file: 17154-34-6.mol

Synonyms:(Diphenylphosphino)trimethylsilane;(Trimethylsilyl)diphenylphosphine; Diphenyl(trimethylsilyl)phosphine

Chemical Property of Diphenyl(trimethylsilyl)phosphine

Chemical Property:

• Vapor Pressure: 0.000457mmHg at 25°C
• Refractive Index: n20/D 1.603(lit.)
• Boiling Point: 119-120 ºC (0.2 mmHg)
• Flash Point: 50 ºF
• PSA: 13.59000
• Density: 1.009
• LogP: 3.95420

Purity/Quality:

99% ^*data from raw suppliers

Diphenyl(trimethylsilyl)phosphine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 11
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of Diphenyl(trimethylsilyl)phosphine

There total 8 articles about Diphenyl(trimethylsilyl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

chloro-trimethyl-silane (75-77-4) + triphenylphosphine (603-35-0) → (trimethylsilyl)diphenylphosphine (17154-34-6)

Guidance literature:

triphenylphosphine; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

chloro-trimethyl-silane; In tetrahydrofuran; for 0.166667h; Inert atmosphere;

DOI:10.1021/ol900222v

Reference yield:

chloro-trimethyl-silane (75-77-4) + diphenylphosphane (829-85-6) → (trimethylsilyl)diphenylphosphine (17154-34-6)

Guidance literature:

With tert-butylimino-tris(dimethylamino)phosphorane; In tetrahydrofuran; diethyl ether; for 24h; Ambient temperature;

Reference yield:

chloro-trimethyl-silane (75-77-4) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → (trimethylsilyl)diphenylphosphine (17154-34-6)

Guidance literature:

chloro-diphenylphosphine; With lithium; In tetrahydrofuran; at 20 ℃; for 3h;

chloro-trimethyl-silane; In tetrahydrofuran; at 0 ℃; for 0.5h;

DOI:10.1039/b500419e

upstream raw materials:

chloro-trimethyl-silane

triphenylphosphine

diphenylphosphane

dibenzofuran

Downstream raw materials:

diphenylphosphanyl-acetonitrile

Diphenyl-(3,3,3-trichloro-2-trimethylsilanyloxy-propyl)-phosphane

Diphenyl-(2,2,2-trichloro-1-trimethylsilanyloxymethyl-ethyl)-phosphane

2,3-bis(diphenylphosphino)maleic anhydride

Refernces

• 1、 Radcliffe, James E.,Batsanov, Andrei S.,Smith, David M.,Scott, John A.,Dyer, Philip W.,Hanton, Martin J.. "Phosphanyl Methanimine (PCN) Ligands for the Selective Trimerization/Tetramerization of Ethylene with Chromium". . p. 7095 - 7098. Retrieved 2015.
• 2、 -. "Synthetic method for bidentate phosphine". Paragraph 0012; 0026; 0030; 0034. . Retrieved 2017/11/18.
• 3、 Brisdon, Alan K.,Herbert, Christopher J.. "A generic route to fluoroalkyl-containing phosphanes". supporting information; experimental part. p. 6658 - 6660. Retrieved 2010/04/01.