rel-2α*-Propyl-3β*-methyloxirane

Base Information

• Chemical Name: rel-2α*-Propyl-3β*-methyloxirane
• CAS No.: 6124-91-0
• Molecular Formula: C6H12O
• Molecular Weight: 100.161
• Hs Code.: 2910900090
• Mol file: 6124-91-0.mol

Synonyms:trans-2-hexene oxide;trans-2,3-Epoxyhexane;trans-2-methyl-3-propyl-oxirane;(E)-2-hexene oxide;trans-2,3-epoxy-hexane;trans-2-hexene epoxide;

Chemical Property of rel-2α*-Propyl-3β*-methyloxirane

Chemical Property:

• PSA: 12.53000
• LogP: 1.57380

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of rel-2α*-Propyl-3β*-methyloxirane

There total 8 articles about rel-2α*-Propyl-3β*-methyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

trans-2-hexene (4050-45-7) → 1,2-Epoxyhexane (1436-34-6) + trans-2,3-epoxyhexane (6124-91-0) + cis-2,3-epoxyhexane (6124-90-9) + butyraldehyde (123-72-8)

Guidance literature:

With oxygen; titanium(IV) oxide; for 19h; Irradiation;

DOI:10.1246/cl.1998.877

Reference yield: 61.0%

cis-2-hexene (7688-21-3) → 1,2-Epoxyhexane (1436-34-6) + trans-2,3-epoxyhexane (6124-91-0) + cis-2,3-epoxyhexane (6124-90-9) + butyraldehyde (123-72-8)

Guidance literature:

With oxygen; titanium(IV) oxide; for 19h; Irradiation;

DOI:10.1246/cl.1998.877

Reference yield:

Cycloheptene (628-92-2,45509-99-7) + 2-hexene (592-43-8) → trans-2,3-epoxyhexane (6124-91-0) + cis-2,3-epoxyhexane (6124-90-9) + 8-oxabicyclo[5.1.0]octane (286-45-3)

Guidance literature:

With dihydrogen peroxide; In water; acetonitrile; optical yield given as %de;

DOI:10.1016/j.apcata.2011.04.044

upstream raw materials:

trans-2-hexene

cis-2-hexene

Cycloheptene

2-hexene

Downstream raw materials:

1-hexene-3-ol

cis-2-hexene

trans-2-hexene

n-hexan-3-ol

Refernces

• 1、 Shiraishi, Yasuhiro,Morishita, Masatsugu,Hirai, Takayuku. "Acetonitrile-assisted highly selective photocatalytic epoxidation of olefins on Ti-containing silica with molecular oxygen". . p. 5977 - 5979. Retrieved 2008/01/27.
• 2、 Ohno, Teruhisa,Kigoshi, Takayo,Nakabeya, Keizo,Matsumura, Michio. "Stereospecific epoxidation of 2-hexene with molecular oxygen on photoirradiated titanium dioxide powder". . p. 877 - 878. Retrieved 2007/10/03.