2-Napthylsulfide

Base Information

• Chemical Name: 2-Napthylsulfide
• CAS No.: 613-81-0
• Molecular Formula: C20H14S
• Molecular Weight: 286.397
• DSSTox Substance ID: DTXSID90459200
• Nikkaji Number: J134.833G
• Wikidata: Q82282895
• Mol file: 613-81-0.mol

Synonyms:2-napthylsulfide;ss-Naphthylsulfid;613-81-0;Di(2-naphthyl) sulfide;SCHEMBL761802;DTXSID90459200;DUZUYBOBIMKSPF-UHFFFAOYSA-N

Chemical Property of 2-Napthylsulfide

Chemical Property:

• XLogP3: 6.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 286.08162162
• Heavy Atom Count: 21
• Complexity: 307

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C=C(C=CC2=C1)SC3=CC4=CC=CC=C4C=C3

Technology Process of 2-Napthylsulfide

There total 11 articles about 2-Napthylsulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

2-Naphthalenethiol (91-60-1) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 2,2'-binaphthalene (612-78-2) + bis(2-naphthyl)sulfide (613-81-0)

Guidance literature:

With tungsten hexacarbonyl; In chlorobenzene; for 35h; Heating;

DOI:10.1021/jo00246a024

Reference yield: 27.0%

2-bromonaphthalene (580-13-2) + ethane-1,2-dithiol (540-63-6) → naphthalene (91-20-3,71998-51-1,72931-45-4) + bis(2-naphthyl)sulfide (613-81-0) + C22H18S2 (85052-78-4)

Guidance literature:

In ammonia; at -33 ℃; for 2h; Irradiation;

DOI:10.1016/S0040-4039(00)95742-3

Reference yield: 14.0%

1,4-Butanedithiol (1191-08-8) + 2-iodonaphthalene (612-55-5) → naphthalene (91-20-3,71998-51-1,72931-45-4) + bis(2-naphthyl)sulfide (613-81-0) + 1,4-bis(naphthalen-2-ylthio)butane (111220-29-2)

Guidance literature:

In ammonia; at -33 ℃; for 2h; Irradiation;

DOI:10.1016/S0040-4039(00)95742-3

upstream raw materials:

2-naphthalenylmagnesium bromide

sodium cyanide

2-naphthalenesulfonic acid sodium salt

isoquinoline

Downstream raw materials:

2,2'-binaphthalene

1,1'-binaphthothiophene

2,2-dinaphthylsulfone

Refernces

• 1、 Lewis, Kevin D.,Rowe, Michael P.,Matzger, Adam J.. "Ethynyl sulfides as participants in cascade cycloaromatizations". . p. 7191 - 7196. Retrieved 2007/10/03.
• 2、 Morrison, Brian J.,Musgrave, Oliver C.. "Thiones as reactive intermediates in condensations of diketones with aromatics mediated by tetraphosphorus decasulfide". . p. 2725 - 2744. Retrieved 2007/10/03.