2-Bromotetradecanoic acid

Base Information

• Chemical Name: 2-Bromotetradecanoic acid
• CAS No.: 10520-81-7
• Deprecated CAS: 135312-82-2
• Molecular Formula: C₁₄H₂₇BrO₂
• Molecular Weight: 307.271
• Hs Code.: 2915900090
• European Community (EC) Number: 234-063-2,681-138-4
• NSC Number: 58380
• DSSTox Substance ID: DTXSID60884484
• Nikkaji Number: J212.448C
• Mol file: 10520-81-7.mol

Synonyms:2-bromomyristic Acid;bromomyristic Acid

Chemical Property of 2-Bromotetradecanoic acid

Chemical Property:

• Appearance/Colour: Off white crystals
• Vapor Pressure: 1.2E-06mmHg at 25°C
• Melting Point: 42 - 45°C
• Boiling Point: 374.7 °C at 760 mmHg
• PKA: 2.97±0.21(Predicted)
• Flash Point: 180.4 °C
• PSA: 37.30000
• Density: 1.147 g/cm³
• LogP: 5.14550
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 306.11944
• Heavy Atom Count: 17
• Complexity: 183

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-BROMOTETRADECANOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCC(C(=O)O)Br

Technology Process of 2-Bromotetradecanoic acid

There total 1 articles about 2-Bromotetradecanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-tetradecanoic acid (544-63-8) → 2-bromomyristic acid (10520-81-7,201417-53-0,135312-82-2)

Guidance literature:

With phosphorus; bromine;

Reference yield: 95.0%

2-bromomyristic acid (10520-81-7,201417-53-0,135312-82-2) → 2-bromotetradecanoic acid chloride (53411-22-6)

Guidance literature:

With oxalyl dichloride; N,N-dimethyl-formamide; In hexane; for 5h; Ambient temperature;

Reference yield: 93.0%

2-bromomyristic acid (10520-81-7,201417-53-0,135312-82-2) + 1,2-bis(o-hydroxyphenoxy)ethane (20115-81-5) → 1,2-di[2-(2'-carboxytetradecyloxy)phenoxy]ethane

Guidance literature:

With sodium hydride; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1016/S0040-4020(99)00514-1

upstream raw materials:

n-tetradecanoic acid

Downstream raw materials:

ethyl 2-bromomyristate

2‐aminotetradecanoic acid

2-Benzamino-tetradecansaeure-⁽¹⁾

1-tridecyl-pyridinium; bromide

Refernces

• 1、 Xianxian, Du. "Syntheses of 2-(2-Hydroxyethylamino) Fatty Acids". . p. 123 - 124. Retrieved 2007/10/02.