Palladium sulfide

Base Information

• Chemical Name: Palladium sulfide
• CAS No.: 12648-43-0
• Deprecated CAS: 59248-14-5
• Molecular Formula: H2PdS
• Molecular Weight: 0
• European Community (EC) Number: 235-190-6
• DSSTox Substance ID: DTXSID00893217
• Wikipedia: Palladium(II)_sulfide
• Wikidata: Q2047949
• Mol file: 12648-43-0.mol

Synonyms:Palladium(II) sulfide;12125-22-3;Palladium sulfide;sulfanylidenepalladium;Palladium sulphide;Palladium sulfide (PdS);Palladium monosulphide;EINECS 235-190-6;Pd-S;DTXSID00893217;MFCD00016285;CS-0080858;Palladium(II) sulfide, 99.9% trace metals basis;J-004472;Q2047949

Chemical Property of Palladium sulfide

Chemical Property:

• Vapor Pressure: 12600mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.00000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 137.87555
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: S=[Pd]

Technology Process of Palladium sulfide

There total 70 articles about Palladium sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) + palladium (7440-05-3) → palladium sulfide (12648-43-0) + sulfur trioxide (7446-11-9)

Guidance literature:

In neat (no solvent); no react. of Pd-asbestos or -sheet with SO2 at room temp.;;

Reference yield:

dichlorobis (dimethyl sulfide) palladium (II) (914979-24-1,14567-23-8,18534-70-8) → hydrogenchloride (7647-01-0,15364-23-5) + palladium sulfide (12648-43-0) + dimethylsulfide (75-18-3)

Guidance literature:

byproducts: CH3Cl; in a stream of N2, at 210 °C, starting of cleavage off of S(CH3)3; at about 260 °C, cleavage off of CH3Cl, ppte. of nearly pure PdS; clevage off of HCl is not observed;;

Reference yield:

sulfur (7704-34-9) + palladium (7440-05-3) → palladium sulfide (12648-43-0)

Guidance literature:

In solid; by heating with S-powder;

upstream raw materials:

carbon oxide sulfide

potassium tetrachloropalladate(II)

sulfur dioxide

palladium

Refernces

• 1、 Khan, Khakemin,Tao, Xiaoping,Zhao, Yue,Zeng, Bin,Shi, Ming,Ta, Na,Li, Jianming,Jin, Xu,Li, Rengui,Li, Can. "Spatial separation of dual-cocatalysts on one-dimensional semiconductors for photocatalytic hydrogen production". . p. 15607 - 15614. Retrieved 2019.
• 2、 Chen, Liu-Cheng,Jiang, Bin-Bin,Yu, Hao,Pang, Hong-Jie,Su, Lei,Shi, Xun,Chen, Li-Dong,Chen, Xiao-Jia. "Thermoelectric properties of polycrystalline palladium sulfide". . p. 13154 - 13158. Retrieved 2018.
• 3、 Zirka,Mashkina. "Liquid-phase hydrogenation of thiophenes on palladium sulfide catalysts". . p. 388 - 393. Retrieved 2000.
• 4、 Jose, Deepa,Jagirdar, Balaji R.. "Synthesis and characterization of Pd(0), PdS, and Pd@PdO core-shell nanoparticles by solventless thermolysis of a Pd-thiolate cluster". . p. 2059 - 2067. Retrieved 2010.
• 5、 Coste, Servane,Hanko, Jason,Bujoli-Doeuff, Martine,Louarn, Guy,Evain, Michel,Brec, Raymond,Alonso, Bruno,Jobic, Stephane,Kanatzidis, Mercouri G.. "NaPdPS4 and RbPdPS4: Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}". . p. 133 - 145. Retrieved 2003.
• 6、 Nayan Sharma, Kamal,Joshi, Hemant,Prakash, Om,Sharma, Alpesh K.,Bhaskar, Renu,Singh, Ajai K.. "Pyrazole-Stabilized Dinuclear Palladium(II) Chalcogenolates Formed by Oxidative Addition of Bis[2-(4-bromopyrazol-1-yl)ethyl] Dichalcogenides to Palladium(II) - Tailoring of Pd-S/Se Nanoparticles". . p. 4829 - 4838. Retrieved 2015.
• 7、 Singhal, Anshu,Dutta, Dimple P.,Tyagi, Avesh K.,Mobin, Shaikh M.,Mathur, Pradeep,Lieberwirth, Ingo. "Palladium(II)/allylpalladium(II) complexes with xanthate ligands: Single-source precursors for the generation of palladium sulfide nanocrystals". . p. 5285 - 5294. Retrieved 2007.
• 8、 Mashkina,Zirka. "Activity of palladium sulfide catalysts in the reaction of gas-phase hydrogenation of 2-methylthiophene". . p. 521 - 526. Retrieved 2000.
• 9、 Ohtani,Ikeda,Hayashi,Fukui. "Mechanochemical preparation of palladium chalcogenides". . p. 1930 - 1934. Retrieved 2007.
• 10、 Ehsan, Muhammad Ali,Ming, Huang Nay,McKee, Vickie,Peiris, Thalge Anton Nirmal,Wijayantha-Kahagala-Gamage, Upul,Arifin, Zainudin,Mazhar, Muhammad. "Vysotskite structured photoactive palladium sulphide thin films from dithiocarbamate derivatives". . p. 4083 - 4091. Retrieved 2014.