Methylsulfide anion

Base Information

• Chemical Name: Methylsulfide anion
• CAS No.: 17302-63-5
• Molecular Formula: CH3 S
• Molecular Weight: 47.1008
• Mol file: 17302-63-5.mol

Synonyms:Methanethiol(1-);Methanethiolate; Methanethiolate anion; Methyl mercaptide; Methyl mercaptylanion; Methyl sulfide anion; Methylthiolate; Thiomethoxide; Thiomethoxide anion

Chemical Property of Methylsulfide anion

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 25.30000
• Density: g/cm³
• LogP: -0.37230

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methylsulfide anion

There total 5 articles about Methylsulfide anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethyldisulphide (624-92-0) → methyl radical (2229-07-4) + ethane (74-84-0) + methylthio radical (7175-75-9) + methanethiolate (17302-63-5)

Guidance literature:

With Co^(1-); under 6E-07 Torr; Product distribution; gas phase reaction;

DOI:10.1021/ja00185a013

Reference yield:

Dimethyldisulphide (624-92-0) → methyl radical (2229-07-4) + ethane (74-84-0) + methylthio radical (7175-75-9) + methanethiolate (17302-63-5)

Guidance literature:

With Fe^(1-); under 6E-07 Torr; Product distribution; gas phase reaction;

DOI:10.1021/ja00185a013

Reference yield:

Dimethyldisulphide (624-92-0) + acetone enolate ion (24262-31-5) → methanethiolate (17302-63-5) + (Z)-1-Methylsulfanyl-propen-2-ol anion

Guidance literature:

at 26.9 ℃; under 0.3 Torr; Product distribution; Mechanism;

DOI:10.1021/ja00186a005

upstream raw materials:

Dimethyldisulphide

acetone enolate ion

(E)-Pent-1-en-1-ol anion

Downstream raw materials:

1-hydroxy-1-phenyl-2-methylthioethane

(+/-)-2-(methylthio)phenethyl alcohol

methylthiol

1,1,1-trifluoroacetone enolate anion

Refernces

• 1、 Grabowski, Joseph J.,Zhang, Lijian. "Dimethyl Disulfide: Anion-Molecule Reactions in the Gas Phase at 300 K". . p. 1193 - 1203. Retrieved 2007/10/02.