Methylthio radical

Base Information

• Chemical Name: Methylthio radical
• CAS No.: 7175-75-9
• Molecular Formula: CH3S
• Molecular Weight: 47.1008
• DSSTox Substance ID: DTXSID60992376
• Nikkaji Number: J276.600K
• Mol file: 7175-75-9.mol

Synonyms:Methylthio radical;CD3S;7175-75-9;methylsulfanyl;DTXSID60992376

Chemical Property of Methylthio radical

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 46.99554627
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[S]

Technology Process of Methylthio radical

There total 8 articles about Methylthio radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethyldisulphide (624-92-0) + methyl disulfide radical (29245-72-5) → dimethyltrisulfane (3658-80-8) + methylthio radical (7175-75-9)

Guidance literature:

Mechanism; Thermodynamic data; 1.) microwave disharge in gas phase 2.) cooled scavenger; Δ_rH;

DOI:10.1002/bbpc.19870910702

Reference yield:

Dimethyldisulphide (624-92-0) → methyl radical (2229-07-4) + ethane (74-84-0) + methylthio radical (7175-75-9) + methanethiolate (17302-63-5)

Guidance literature:

With Co^(1-); under 6E-07 Torr; Product distribution; gas phase reaction;

DOI:10.1021/ja00185a013

Reference yield:

Dimethyldisulphide (624-92-0) → methyl radical (2229-07-4) + ethane (74-84-0) + methylthio radical (7175-75-9) + methanethiolate (17302-63-5)

Guidance literature:

With Fe^(1-); under 6E-07 Torr; Product distribution; gas phase reaction;

DOI:10.1021/ja00185a013

upstream raw materials:

Dimethyldisulphide

diphenylcarbene

methyl radical

methyl disulfide radical

Downstream raw materials:

methyl thionitrate

Methanesulfenyl chloride

clorine

nitrogen(II) oxide

Refernces

• 1、 Sallans, L.,Lane, K. R.,Freiser, B. S.. "Gas-Phase Reactions of Fe(1-) and Co(1-) with Simple Thiols, Sulfides, and Disulfides by Fourier Transform Mass Spectrometry". . p. 865 - 873. Retrieved 2007/10/02.
• 2、 Alberti, A.,Griller, D.,Nazran, A. S.,Pedulli, G. F.. "Reactions of Triplet Carbenes with Sulfides and Disulfides: Ylide vs. Radical Formation". . p. 3024 - 3028. Retrieved 2007/10/02.