Methyl hydrazino(oxo)acetate

Base Information

• Chemical Name: Methyl hydrazino(oxo)acetate
• CAS No.: 63970-76-3
• Molecular Formula: C3H6N2O3
• Molecular Weight: 118.092
• Hs Code.: 2928000090
• European Community (EC) Number: 818-771-4
• DSSTox Substance ID: DTXSID20463239
• Nikkaji Number: J1.811.908K
• Wikidata: Q82288083
• Mol file: 63970-76-3.mol

Synonyms:Methyl hydrazino(oxo)acetate;63970-76-3;methyl 2-hydrazinyl-2-oxoacetate;methyl (hydrazinecarbonyl)formate;C3H6N2O3;methyl hydrazino-oxo-acetate;SCHEMBL2072093;methyl2-hydrazinyl-2-oxoacetate;DTXSID20463239;MFCD01597248;AKOS005174264;VS-02852;CS-0265222;FT-0683846;EN300-97063

Chemical Property of Methyl hydrazino(oxo)acetate

Chemical Property:

• PSA: 81.42000
• LogP: -0.75950
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• XLogP3: -0.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 118.03784206
• Heavy Atom Count: 8
• Complexity: 111

Purity/Quality:

98%min ^*data from raw suppliers

methylhydrazino(oxo)acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C(=O)NN

Technology Process of Methyl hydrazino(oxo)acetate

There total 3 articles about Methyl hydrazino(oxo)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

→ methyl hydrazino(oxo)acetate (63970-76-3)

Guidance literature:

Reference yield:

Dimethyl oxalate (553-90-2) → oxalic acid hydrazide (996-98-5) + methyl hydrazino(oxo)acetate (63970-76-3)

Guidance literature:

With hydrazine hydrate; In methanol; 1.) -30 to -20 deg C, 1 h, 2.) to 35 deg C, 40 min;

Reference yield:

Dimethyl oxalate (553-90-2) → methyl hydrazino(oxo)acetate (63970-76-3)

Guidance literature:

With hydrazine hydrate; In methanol;

DOI:10.1021/jm50018a004

upstream raw materials:

Dimethyl oxalate

Downstream raw materials:

oxalamic acid hydrazide

Oxalsaeure-hydrazid-

Oxalsaeurehydrazid-

2-(Methoxyoxalylhydrazono)-2-phenylessigsaeure

Refernces

• 1、 Christl, Manfred,Lanzendoerfer, Ulrike,Groetsch, Maria M.,Ditterich, Elke,Hegmann, Joachim. "Cycloadditions of 1,3,4-Oxadiazin-6-ones (4,5-Diaza-α-pyrones), 9. - Methyl 6-Oxo-5-phenyl-1,3,4-oxadiazin-2-carboxylate - Synthesis and Reactions with Norbornene, Norbornadiene, Cyclopropenes, Cyclobutene, and Benzvalene". . p. 2031 - 2037. Retrieved 2007/10/02.