Carbamic acid, (chlorothio)methyl-, butyl ester

Base Information

• Chemical Name: Carbamic acid, (chlorothio)methyl-, butyl ester
• CAS No.: 64831-38-5
• Molecular Formula: C₆H₁₂ClNO₂S
• Molecular Weight: 197.686
• Mol file: 64831-38-5.mol

Synonyms:N-Methyl-N-chlorthio-n-butylcarbamat;n-butyl N-chlorothio-N-methylcarbamate;

Chemical Property of Carbamic acid, (chlorothio)methyl-, butyl ester

Chemical Property:

• PSA: 67.12000
• LogP: 2.56160

Purity/Quality:

ButylN-(Chlorosulfenyl)-N-methylcarbamate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Butyl N-(Chlorosulfenyl)-N-methylcarbamate is an intermediate in synthesizing Furathiocarb (F863780), a pesticide.

Technology Process of Carbamic acid, (chlorothio)methyl-, butyl ester

There total 1 articles about Carbamic acid, (chlorothio)methyl-, butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ n-butyl N-chlorothio-N-methylcarbamate (64831-38-5)

Guidance literature:

N-Methyl-n-butylcarbamat, SCl2;

DOI:10.1021/jf60217a021

Reference yield: 83.4%

N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine (403612-83-9) + n-butyl N-chlorothio-N-methylcarbamate (64831-38-5) → CH3(CH2)3OCON(CH3)SN(N(C(CH3)3)COC6H5)COC5H4FeC5H5 (403612-88-4)

Guidance literature:

With sodium hydride; In tetrahydrofuran; (N2); addn. of NaH to a soln. of iron complex in THF, stirring at room temp. for 0.5 h, cooling to 0°C, addn. of a soln. of carbamate in THF, stirring for 8 h at room temp.; filtration, concn., column chromy (SiO2, petroleum ether/ethyl acetate);elem. anal.;

DOI:10.1016/S0022-328X(01)00876-2

Reference yield:

N-(2,4-dimethylphenyl)-N′-methylformamidine (33089-74-6) + n-butyl N-chlorothio-N-methylcarbamate (64831-38-5) → C16H25N3O2S (60358-11-4)

Guidance literature:

With pyridine;

Downstream raw materials:

C₁₆H₂₅N₃O₂S

C₁₅H₂₂ClN₃O₂S

C₁₄H₁₉Cl₂N₃O₂S

C₁₅H₂₂ClN₃O₂S