N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine

Base Information

• Chemical Name: N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine
• CAS No.: 403612-83-9
• Molecular Formula: C₂₂H₂₄FeN₂O₂
• Molecular Weight: 404.292
• Mol file: 403612-83-9.mol

Synonyms:

Chemical Property of N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine

There total 2 articles about N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

ferrocenoyl chloride (1293-79-4) + N'-t-butyl-N'-benzoylhydrazine (99981-48-3) → N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine (403612-83-9)

Guidance literature:

With triethylamine; In tetrahydrofuran; (N2); addn. of a soln. of iron complex in THF to a soln. of hydrazine compd. with amine in THF at 0°C, stirring at room temp. for 8 h; filtration, concn., column chromy (SiO2, petroleum ether/ethyl acetate);elem. anal.;

DOI:10.1016/S0022-328X(01)00876-2

Reference yield:

ferrocenecarboxylic acid anhydride + N'-t-butyl-N'-benzoylhydrazine (99981-48-3) → N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine (403612-83-9)

Guidance literature:

DOI:10.1016/S0022-328X(01)00876-2

Reference yield: 83.4%

N-tert-butyl-N'-ferrocenoyl-N-benzoylhydrazine (403612-83-9) + n-butyl N-chlorothio-N-methylcarbamate (64831-38-5) → CH3(CH2)3OCON(CH3)SN(N(C(CH3)3)COC6H5)COC5H4FeC5H5 (403612-88-4)

Guidance literature:

With sodium hydride; In tetrahydrofuran; (N2); addn. of NaH to a soln. of iron complex in THF, stirring at room temp. for 0.5 h, cooling to 0°C, addn. of a soln. of carbamate in THF, stirring for 8 h at room temp.; filtration, concn., column chromy (SiO2, petroleum ether/ethyl acetate);elem. anal.;

DOI:10.1016/S0022-328X(01)00876-2

upstream raw materials:

ferrocenoyl chloride

N'-t-butyl-N'-benzoylhydrazine

Downstream raw materials:

CH₃CH₂OCON(CH₃)SN(N(C(CH₃)3)COC₆H₅)COC₅H₄FeC₅H₅

CH₃(CH₂)3OCON(CH₃)SN(N(C(CH₃)3)COC₆H₅)COC₅H₄FeC₅H₅

Refernces