Boranamine, 1,1-dichloro-N,N-bis(trimethylsilyl)-

Base Information

• Chemical Name: Boranamine, 1,1-dichloro-N,N-bis(trimethylsilyl)-
• CAS No.: 6591-26-0
• Molecular Formula: C6H18BCl2NSi2
• Molecular Weight: 242.104
• DSSTox Substance ID: DTXSID50448897
• Nikkaji Number: J2.040.983E,J3.377.876G
• Wikidata: Q82268092
• Mol file: 6591-26-0.mol

Synonyms:6591-26-0;Boranamine, 1,1-dichloro-N,N-bis(trimethylsilyl)-;[[dichloroboranyl(trimethylsilyl)amino]-dimethylsilyl]methane;N-(DICHLOROBORYL)HEXAMETHYLDISILAZANE;N-(Dichloroboryl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;SCHEMBL6429292;DTXSID50448897;Bis(trimethylsilyl)aminodichloroborane;Bis-(trimethylsilyl)-amino-dichlorboran;Bis(trimethylsilyl)iminiodichloroboronanion

Chemical Property of Boranamine, 1,1-dichloro-N,N-bis(trimethylsilyl)-

Chemical Property:

• Melting Point: 5-6°C
• Refractive Index: 1.4554
• Boiling Point: 82°C / 11
• PSA: 3.24000
• LogP: 3.42070
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 241.0447882
• Heavy Atom Count: 12
• Complexity: 139

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(N([Si](C)(C)C)[Si](C)(C)C)(Cl)Cl

Technology Process of Boranamine, 1,1-dichloro-N,N-bis(trimethylsilyl)-

There total 2 articles about Boranamine, 1,1-dichloro-N,N-bis(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(C2H5)3N*BCl3 + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → bis(trimethylsilyl)aminodichloroborane (6591-26-0) + triethylamine hydrochloride (554-68-7)

Guidance literature:

With triethylamine; In benzene; N(C2H5)3 in excess;

DOI:10.1021/ic50042a006

Reference yield:

tris(trimethylsilyl)amine (1586-73-8) + boron trichloride (10294-34-5) → chloro-trimethyl-silane (75-77-4) + N-(chlorodimethylsilyl)-N,N-bis(trimethylsilyl)amine (1586-72-7) + Bis(chlordimethylsilyl)(trimethylsilyl)amin (18790-09-5) + bis(trimethylsilyl)aminodichloroborane (6591-26-0)

Guidance literature:

React. of starting materials (vac., room temp., 20 h).; Sepn. of volatile materials by fractional condensation. Identification by mass spectroscopy.;

Reference yield: 89.0%

bis(trimethylsilyl)aminodichloroborane (6591-26-0) + dicyclohexyl-carbodiimide (538-75-0) → [((CH3)3Si)2NC(N(C6H11))2]BCl2 (883561-95-3)

Guidance literature:

In diethyl ether; hexane; all manipulations under dry, oxygen-free Ar atm.; soln. of B compd. in hexane added to soln. of org. compd. in Et2O at ambient temp., stirred overnight at room temp.; solvent removed in vac.; elem. anal.;

DOI:10.1016/j.poly.2005.11.012

upstream raw materials:

tris(trimethylsilyl)amine

boron trichloride

1,1,1,3,3,3-hexamethyl-disilazane

Downstream raw materials:

chloro-trimethyl-silane

2,4,6-trichloro-1,3,5-tris(trimethylsilyl)borazine

(bis(trimethylsilyl)amino)((trimethylsilyl)amino)chloroborane

tris(trimethylsilyl)amine

Refernces

• 1、 Wells, Richard L.,Collins, Alva L.. "Dehydrohalogenation and cleavage reactions in silicon-nitrogen-boron systems". . p. 1327 - 1328. Retrieved 2007/10/14.