(4-Methoxyphenoxy)trimethylsilane

Base Information

• Chemical Name: (4-Methoxyphenoxy)trimethylsilane
• CAS No.: 6689-38-9
• Molecular Formula: C10H16O2Si
• Molecular Weight: 196.321
• Hs Code.: 2931900090
• Mol file: 6689-38-9.mol

Synonyms:p-Methoxyphenyltrimethylsilylaether;

Chemical Property of (4-Methoxyphenoxy)trimethylsilane

Chemical Property:

• Boiling Point: 112 °C(Press: 12 Torr)
• PSA: 18.46000
• Density: 1.0056 g/cm3
• LogP: 2.90890

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (4-Methoxyphenoxy)trimethylsilane

There total 17 articles about (4-Methoxyphenoxy)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-methoxy-phenol (150-76-5) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → (4-methoxyphenoxy)trimethylsilane (6689-38-9)

Guidance literature:

With trichloromelamine; In dichloromethane; acetonitrile; at 20 ℃; for 5h;

DOI:10.1002/jccs.200900037

Reference yield: 99.0%

trimethylsilyl formate (18243-21-5) + 4-methoxy-phenol (150-76-5) → (4-methoxyphenoxy)trimethylsilane (6689-38-9)

Guidance literature:

With [Ru(κ¹-OAc)(κ²-OAc)(κ³-1,1,1-tris(diphenylphosphinomethyl)ethane)]; In acetonitrile; at 70 ℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;

Reference yield: 98.0%

4-methoxy-phenol (150-76-5) + lithium hexamethyldisilazane (4039-32-1) → (4-methoxyphenoxy)trimethylsilane (6689-38-9)

Guidance literature:

With N-chlorosaccharin; In neat (no solvent); at 20 ℃; for 0.0666667h;

DOI:10.1002/jccs.201300624

upstream raw materials:

chloro-trimethyl-silane

4-methoxy-phenol

sodium 4-methoxyphenolate

1-bromo-4-methoxy-benzene

Downstream raw materials:

chloro-trimethyl-silane

4-methoxyphenyl 2-methylpropionate

4-methoxyphenyl 2,2-dimethylpropionate

4-methoxyphenyl 3-methylbutanoate

Refernces

• 1、 Moores, Lee C.,Kaur, Devinder,Smith, Mathew D.,Poole, James S.. "Regioselectivity of Hydroxyl Radical Reactions with Arenes in Nonaqueous Solutions". . p. 3260 - 3269. Retrieved 2019/03/11.
• 2、 Zolfigol, Mohammad Ali,Sajjadifar, Sami,Ghorbani-Choghamarani, Arash,Tami, Farzaneh. "Application of a novel nano-immobilization of ionic liquid on an MCM-41 system for trimethylsilylation of alcohols and phenols with hexamethyldisilazane". . p. 7093 - 7106. Retrieved 2018/08/17.