Hypofluorous acid, methyl ester (9CI)

Base Information

• Chemical Name: Hypofluorous acid, methyl ester (9CI)
• CAS No.: 36336-08-0
• Molecular Formula: CH3 F O
• Molecular Weight: 50.0326
• Mol file: 36336-08-0.mol

Synonyms:Methylhypofluorite

Chemical Property of Hypofluorous acid, methyl ester (9CI)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 0.879g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hypofluorous acid, methyl ester (9CI)

There total 1 articles about Hypofluorous acid, methyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methanol (67-56-1) → methyl hypofluorite (36336-08-0)

Guidance literature:

With fluorine; In various solvent(s); at -78 ℃; for 0.833333h;

DOI:10.1021/ja00007a043

Reference yield: 90.0%

1,2,4,5-tetramethylbenzene (95-93-2) + methyl hypofluorite (36336-08-0) → 2,3,5,6-tetramethylanisole (14337-37-2)

Guidance literature:

In dichloromethane; acetonitrile; -45 deg C to room temperature;

DOI:10.1021/jo00058a052

Reference yield: 87.0%

α-methoxystyrene (4747-13-1) + methyl hypofluorite (36336-08-0) → 1-phenyl-1,1,2-trimethoxyethane (143191-51-9)

Guidance literature:

In chloroform; acetonitrile; at -40 - 20 ℃;

upstream raw materials:

methanol

Downstream raw materials:

fluoro-1, methoxy-2, phenyl-1 ethane

2,3,5,6-tetramethylanisole

pentamethylbenzyl methyl ether

1,2-bis-methoxymethyl-3,4,5,6-tetramethyl-benzene

Refernces

• 1、 Kol, Moshe,Rozen, Shlomo. "Functionalization of Aromatic Molecules Using HOF*CH3CN and CH3OF". . p. 1593 - 1595. Retrieved 2007/10/02.
• 2、 Kol, Moshe,Rozen, Shlomo,Appelman, Evan. "Isolation and characterization of methyl hypofluorite (CH3OF)". . p. 2648 - 2651. Retrieved 2007/10/02.