4747-13-1

Basic information

• Product Name: Methyl(1-phenylethenyl) ether
• Synonyms: (1-Methoxyethenyl)benzene;(1-Methoxyvinyl)benzene;1-Methoxy-1-phenylethene;Methyl 1-phenylvinyl ether;Methyl(1-phenylethenyl) ether
• CAS NO: 4747-13-1
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.18
• Mol File: 4747-13-1.mol
• Article Data: 45

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Methyl(1-phenylethenyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl(1-phenylethenyl) ether(4747-13-1)
• EPA Substance Registry System: Methyl(1-phenylethenyl) ether(4747-13-1)

Safety Data

• Hazardous Substances Data: 4747-13-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 1738, 1955 DOI: 10.1021/ja01612a006Synthesis, p. 144, 1988 DOI: 10.1055/s-1988-27495Tetrahedron Letters, 23, p. 631, 1982 DOI: 10.1016/S0040-4039(00)86908-7

Upstream product

• 13684-98-5 2-methoxy-2-phenylethyl iodide 
• 13685-00-2 1-(2-bromo-1-methoxyethyl)benzene 
• 4316-35-2 acetophenone dimethyl acetal 
• 104-15-4 toluene-4-sulfonic acid 
• 100-42-5 styrene 
• 67-56-1 methanol 
• 124-41-4 sodium methylate 
• 5925-76-8 selenobenzoic acid O-methyl ester 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 98-86-2 acetophenone 
• 149-73-5 trimethyl orthoformate 
• 536-74-3 phenylacetylene 
• 101-41-7 benzeneacetic acid methyl ester 
• 14452-30-3 3'-iodoacetophenone 

Downstream Products

• 942-92-7 caprophenone 
• 1669-49-4 3-(4-methoxyphenyl)-1-phenylpropan-1-one 
• 5653-09-8 2-cyclohexyl-1-phenylethan-1-one 
• 1533-20-6 1,3-diphenylbutane-1-one 
• 606-86-0 1,3,3-triphenylpropan-1-one 
• 2492-30-0 acetophenone semicarbazone 
• 612-71-5 1,3,5-triphenylbenzene 
• 93-55-0 1-phenyl-propan-1-one 
• 15982-59-9 2-methyl-1,4-diphenylbutane-1,4-dione 
• 74-83-9 methyl bromide 
• 1083-30-3 dihydrochalcone 
• 6270-17-3 ethyl 3-benzoylpropanoate 
• 854211-65-7 (β-methoxy-styryl)-hydrazine-N,N'-dicarboxylic acid dimethyl ester 
• 495-71-6 phenacylacetophenone 

Relevant articles and documents

New Surprises with Fischer Carbene Complexes: Formal [3 + 2] Cycloadditions with and without Preceding Carbene-Ligand Metathesis

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Photoinduced Cross-Coupling of Aryl Iodides with Alkenes

A protocol for photoinduced cross-coupling of aryl iodides having polar π-functional groups or elongated π-conjugation with alkenes has been developed. The radical cascade mechanism involving generation of aryl radicals via C-I bond homolysis of photoexcited aryl iodides and their subsequent addition to alkenes is proposed. The method enables iodide-selective cross-coupling over other halogen leaving groups with functional group compatibility on both arene and alkene motifs.

Reactions of Cp2TiMe2 with ferrocene and (n5-Cp)Co(n4-C4Ph4) derived esters and amides: A new route for 1-methylvinyl and methyl ketone derived metal sandwich compounds

Reactions of Cp2TiMe2, with the ester derivatives of organometallic sandwich compounds (n5-RC5H4)Fe(n5-C5H5) and (n5-RC5H4)Co(n4-C4Ph4) (R=ester groups) gave products having R=C(CH2)Me, instead of the expected vinyl ethers indicating conversion of the ester units by Cp2TiMe2 to methyl ketones followed by methylenation. A reaction of Cp2TiMe2 with the diester (n5-RC5H4)Co(n4-C4Ph3R)(R=C(O)OMe) also gave similar results. The study has also been successfully extended to metal sandwich derived amides, thio and seleno esters. By controlling the amount of Cp2TiMe2, the reactions were also stopped at the methyl ketone stage and the methyl ketones were isolated in good yields and characterized. The method provides an easy and direct access to convert organometallic sandwich derived esters and related compounds to 1-methylvinyl derived products.