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93-55-0Relevant articles and documents
Porous Cu-BTC silica monoliths as efficient heterogeneous catalysts for the selective oxidation of alkylbenzenes
Song, Guo-Qiang,Lu, Ying-Xun,Zhang, Qi,Wang, Fan,Ma, Xiao-Kun,Huang, Xian-Feng,Zhang, Zhi-Hui
, p. 30221 - 30224 (2014)
The microporous material Cu-BTC (1,3,5-benzenetricarboxylic acid, BTC) is a prototype metal-organic framework (MOF). In situ combination of Cu-BTC and macro-/mesoporous silica monoliths lead to an efficient catalyst for selective oxidation. The catalytic
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Roberts,Brandenberger
, p. 5484,5485 (1957)
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A Rhodium Complex That Combines Benzene Activation with Ethylene Insertion. Subsequent Carbonylation and Ketone Formation
Ghosh, Chanchal K.,Graham, William A. G.
, p. 375 - 376 (1989)
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Ohki et al.
, p. 766,767 (1979)
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ORGANO CYANOCUPRATES. II. REACTIONS AVEC LES CETONES α-HALOGENEES
Hamon, Louis,Levisalles, Jacques
, p. 259 - 272 (1983)
Comparison of lithium dimethylcuprate versus methylcyanocuprate as nucleophilic methylating reagents for α-halo ketones shows better selectivity for alkylation in the case of methylcyanocuprate, especially in the mixed solvent ether/dimethylformamide.The inverse addition techniques and addition of ligands such as dimethyl maleate also improve the selectivity.Methylcopper in the presence of chelating agents gives good selectivity but the reaction is slower.
Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups
Xu, Weixia,Zhang, Zengqi,Zhao, Xin,Li, Jun
, p. 746 - 755 (2017)
One metal-free porphyrin, modified by electron-withdrawing groups, was synthesized by introduction of two peripheral pyridyl substituents and two metal coordination polymers, {[Zn(C42H16F10N6)]·2C2Hs
A Novel Open-Framework Copper Borovanadate with Enhanced Catalytic Performance for Oxidation of Benzylic C?H Bond
Feng, Yuquan,Zhong, Zhiguo,Wang, Hongwei,Fan, Huitao,Bi, Dongqin,Wang, Lu,Xing, Zhengzheng,Qiu, Dongfang
, p. 9962 - 9967 (2017)
A novel open-framework copper borovanadate, with a 6-connected topological net and 1D 8-membered ring channels, has been obtained for the first time. The compound not only exhibits a unique -B3O7(OH)-Cu-B(OH)3 linkage and
Efficient and selective oxidation of hydrocarbons with tert-butyl hydroperoxide catalyzed by oxidovanadium(IV) unsymmetrical Schiff base complex supported on γ-Fe2O3 magnetic nanoparticles
Ardakani, Mehdi Hatefi,Sabet, Mohammad,Samani, Mahnaz
, (2022/01/22)
The catalytic activity of an oxidovanadium(IV) unsymmetrical Schiff base complex supported on γ-Fe2O3 magnetic nanoparticles, γ-Fe2O3@[VO(salenac-OH)] in which salenac-OH = [9-(2′,4′-dihydroxyphenyl)-5,8-diaza-4
Cyclometalated (NNC)Ru(ii) complex catalyzed β-methylation of alcohols using methanol
Belkova, Natalia V.,Ganguli, Kasturi,Kundu, Sabuj
supporting information, p. 4354 - 4365 (2022/04/07)
Indolyl fragment containing phenanthroline based new ligands and their corresponding Ru(ii) complexes were synthesized and fully characterized by various spectroscopic techniques. The catalytic activity of these newly synthesized cyclometalated (NNC)Ru(ii) complexes was explored towards the β-methylation of alcohols using methanol. Notably, these complexes displayed superior reactivity compared to various (NNN)Ru(ii) complexes. Utilizing this strategy, a wide range of primary, secondary, and aliphatic straight chain alcohols were selectively methylated. This protocol was further employed for the methylation of a few natural products and the gram scale synthesis of β-methylated alcohols. A series of control experiments and kinetic studies were performed to understand the plausible reaction mechanism.
Gold complexes of bis-indazole-derived N-Heterocyclic carbene: Synthesis, structural characterizations, and catalysis
Zhang, Hua,Xu, Ting,Li, Dongdong,Cheng, Tao,Chen, Jing,Zhou, Yang
, (2021/02/26)
A novel series of bis Indy-NHC gold complexes have been developed and investigated via a mild Ag-carbene transfer route. The obtained complexes were characterized by NMR spectroscopy and X-ray diffraction analysis. The catalytic property of these gold complexes was further evaluated in the oxidation of benzylic. The gold complex E1 showed a high catalytic activity in the oxidation of various benzylic substrates, resulting in the corresponding carbonyl compounds with excellent yields using TBHP as oxidant.