5-Hexadecenoic acid, (E)-

Base Information

• Chemical Name: 5-Hexadecenoic acid, (E)-
• CAS No.: 7056-84-0
• Molecular Formula: C16H30O2
• Molecular Weight: 254.413
• Mol file: 7056-84-0.mol

Synonyms:

Chemical Property of 5-Hexadecenoic acid, (E)-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-Hexadecenoic acid, (E)-

There total 18 articles about 5-Hexadecenoic acid, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tert-Butyl-[((E)-hexadec-5-enyl)oxy]-diphenyl-silane (1026489-01-9) → (E)-5-Hexadecenoic acid (7056-84-0)

Guidance literature:

With jones reagent; at 25 ℃; for 12h;

DOI:10.1016/S0040-4039(99)00895-3

Reference yield: 84.0%

(E)-Hexadec-5-enal (99142-11-7) → (E)-5-Hexadecenoic acid (7056-84-0)

Guidance literature:

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; Ambient temperature;

DOI:10.1021/jo00281a026

Reference yield: 58.0%

(E)-pentadec-4-en-1-ol (85388-16-5) → (E)-5-Hexadecenoic acid (7056-84-0)

Guidance literature:

With dipyridinium dichromate; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetasy.2014.03.006

upstream raw materials:

(E)-Hexadec-5-enal

tert-Butyl-[((E)-hexadec-5-enyl)oxy]-diphenyl-silane

3,4,5,6-tetrahydro-2H-pyran-2-one

5-hydroxypentanal

Downstream raw materials:

racemic threo 6-acetoxy-5-hexadecanolide

(5S,6R)-6-hydroxy-5-hexadecanolide

(5R,6S)-6-hydroxy-5-hexadecanolide-4-nitrobenzoate

(5S,6R)-6-hydroxy-5-hexadecanolide 4-nitrobenzoate

Refernces

• 1、 -. "Metathesis syntheses of pheromones or their components". . . Retrieved 2008/06/13.
• 2、 Couladourosand, Elias A.,Mihou, Anastasia P.. "A general synthetic route towards γ- and δ-lactones. Total asymmetric synthesis of (-)-muricatacin and the mosquito oviposition pheromone (5R, 6s)- 6-acetoxy-hexadecanolide". . p. 4861 - 4862. Retrieved 2007/10/03.