Benzoyl azide, 4-(dimethylamino)-

Base Information

• Chemical Name: Benzoyl azide, 4-(dimethylamino)-
• CAS No.: 70843-95-7
• Molecular Formula: C9H10N4O
• Molecular Weight: 190.205
• Mol file: 70843-95-7.mol

Synonyms:

Chemical Property of Benzoyl azide, 4-(dimethylamino)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoyl azide, 4-(dimethylamino)-

There total 5 articles about Benzoyl azide, 4-(dimethylamino)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.6%

4-(dimethylamino)benzoyl chloride (4755-50-4) → azido(4-(dimethylamino)phenyl)methanone (70843-95-7)

Guidance literature:

With sodium azide; In water; acetone; for 1h; Cooling with ice;

Reference yield: 78.0%

4-dimethylamino-benzaldehyde (100-10-7) → azido(4-(dimethylamino)phenyl)methanone (70843-95-7)

Guidance literature:

With manganese(IV) oxide; sodium azide; tetrachlorosilane; In dichloromethane; at 0 ℃;

DOI:10.1016/0040-4039(94)02472-N

Reference yield: 29.0%

C11H13NO4 → azido(4-(dimethylamino)phenyl)methanone (70843-95-7)

Guidance literature:

With sodium azide; In water; at 0 ℃; for 1h;

DOI:10.1021/jm00171a035

upstream raw materials:

4-(dimethylamino)benzohydrazide

4-dimethylamino-benzaldehyde

4-(dimethylamino)benzoyl chloride

methyl 4-(N,N-dimethylamino)benzoate

Downstream raw materials:

N,N-dimethylaminophenyl isocyanate

<3-<4-(dimethylamino)phenyl>-2-oxo-5-oxazolidinyl>methyl azide

N-(4-(dimethylamino)phenyl)-2-phenylpropanamide

4‐[4‐(dimethylamino)phenyl]‐4,5‐dihydro‐3H‐1,2,4‐triazole‐3,5‐dione

Refernces

• 1、 -. "METHOD FOR PRODUCING SEMICARBAZIDE COMPOUND". Paragraph 0076-0078. . Retrieved 2021/01/20.
• 2、 Elmorsy, Saad S.. "Oxidation of aldehydes to acyl azides using triazidochlorosilane (TACS)-active manganese dioxide reagent". . p. 1341 - 1342. Retrieved 2007/10/02.