1-(4-Bromophenyl)-2-(hydroperoxyphenylmethyl)diazene

Base Information

• Chemical Name: 1-(4-Bromophenyl)-2-(hydroperoxyphenylmethyl)diazene
• CAS No.: 72437-42-4
• Deprecated CAS: 154055-81-9
• Molecular Formula: C13H11BrN2O2
• Molecular Weight: 307.147
• UNII: A8QL7V05ZZ
• DSSTox Substance ID: DTXSID10501790
• Nikkaji Number: J568.040I
• Wikidata: Q27896125
• Mol file: 72437-42-4.mol

Synonyms:72437-42-4;A8QL7V05ZZ;1-(4-Bromophenyl)-2-(hydroperoxyphenylmethyl)diazene;UNII-A8QL7V05ZZ;Hydroperoxide, ((4-bromophenyl)azo)phenylmethyl;Diazene, 1-(4-bromophenyl)-2-(hydroperoxyphenylmethyl)-;DTXSID10501790;[(E)-(4-Bromophenyl)diazenyl](phenyl)methaneperoxol;Q27896125

Chemical Property of 1-(4-Bromophenyl)-2-(hydroperoxyphenylmethyl)diazene

Chemical Property:

• PSA: 54.18000
• LogP: 4.72120
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 306.00039
• Heavy Atom Count: 18
• Complexity: 262

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(N=NC2=CC=C(C=C2)Br)OO

Technology Process of 1-(4-Bromophenyl)-2-(hydroperoxyphenylmethyl)diazene

There total 3 articles about 1-(4-Bromophenyl)-2-(hydroperoxyphenylmethyl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.5%

benzaldehyde 4-bromophenylhydrazone (16917-43-4) → [(4-bromophenyl)diazenyl](phenyl)methyl hydroperoxide (72437-42-4)

Guidance literature:

With oxygen; In benzene; at 20 ℃; for 6h;

DOI:10.1016/S0968-0896(02)00048-2

Reference yield:

4-bromophenylhydrazine hydrochloride (622-88-8,41931-18-4) → [(4-bromophenyl)diazenyl](phenyl)methyl hydroperoxide (72437-42-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / sodium acetate / H₂O; ethanol / 20 °C

2: 60.5 percent / O₂ / benzene / 6 h / 20 °C

With oxygen; sodium acetate; In ethanol; water; benzene;

DOI:10.1016/S0968-0896(02)00048-2

Reference yield:

benzaldehyde (100-52-7) → [(4-bromophenyl)diazenyl](phenyl)methyl hydroperoxide (72437-42-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / sodium acetate / H₂O; ethanol / 20 °C

2: 60.5 percent / O₂ / benzene / 6 h / 20 °C

With oxygen; sodium acetate; In ethanol; water; benzene;

DOI:10.1016/S0968-0896(02)00048-2

upstream raw materials:

benzaldehyde 4-bromophenylhydrazone

4-bromophenylhydrazine hydrochloride

benzaldehyde

Downstream raw materials:

2-(4-bromophenyl]pyridine

N'-(p-bromophenyl)benzohydrazide

N-(4-bromophenyl)-N'-benzoyldiazene

benzoic acid

Refernces

• 1、 Tezuka, Takahiro,Iwaki, Masaaki. "A New Epoxidation Reaction: Base-catalysed Stereospecific Epoxidation with α-Azohydroperoxides". . p. 2507 - 2509. Retrieved 2007/10/02.