Diphenylethylsilane

Base Information

• Chemical Name: Diphenylethylsilane
• CAS No.: 7535-07-1
• Molecular Formula: C14H16Si
• Molecular Weight: 212.367
• European Community (EC) Number: 660-328-0
• Mol file: 7535-07-1.mol

Synonyms:diphenylethylsilane;AKOS024338735

Chemical Property of Diphenylethylsilane

Chemical Property:

• Vapor Pressure: 0.00504mmHg at 25°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 212.102127045
• Heavy Atom Count: 15
• Complexity: 148

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[SiH](C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Diphenylethylsilane

There total 9 articles about Diphenylethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

dichlorophenylsilane (1631-84-1) + ethylmagnesium bromide (925-90-6) → diphenyl(ethyl)silane (7535-07-1)

Guidance literature:

In diethyl ether; at 0 - 20 ℃; for 1h;

DOI:10.1021/acs.organomet.6b00067

Reference yield: 24.0%

triethylsilane (617-86-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → diethylphenylsilane (16545-43-0) + diphenyl(ethyl)silane (7535-07-1)

Guidance literature:

With [cis-{(η⁵-C₅H₃)₂(CMe₂)₂}Ru₂(κ²-(4,4′-di-tertbutyl)-2,2′-bipyridine)₂(μ-H)][OTf]; mercury; at 175 ℃; for 24h;

DOI:10.1021/acs.organomet.6b00067

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + phenylsilane (694-53-1) → diphenyl(ethyl)silane (7535-07-1) + (1-octyl)(phenyl)silane (18415-18-4)

Guidance literature:

With zirconocene dichloride; ethylmagnesium bromide; In tetrahydrofuran; at 25 ℃; for 1h;

DOI:10.1021/ja00022a077

upstream raw materials:

ethyldichlorosilane

oct-1-ene

phenylsilane

diphenylsilane

Downstream raw materials:

ethyl-diphenyl-prop-1-enyloxy-silane

Methylphosphonsaeure-bis-(aethyl-diphenyl-silylester)

chloro(ethyl)(diphenyl)silane

ethoxy(ethyl)(diphenyl)silane

Refernces

• 1、 Price, Jeffrey S.,Emslie, David J. H.. "Interconversion and reactivity of manganese silyl, silylene, and silene complexes". . p. 10853 - 10869. Retrieved 2019/12/23.
• 2、 Takahashi, Tamotsu,Hasegawa, Maki,Suzuki, Noriyuki,Saburi, Masahiko,Rousset, Christophe J.,Fanwick, Phillip E.,Negishi, Ei-Ichi. "Zirconium-catalyzed, highly regioselective hydrosilation reaction of alkenes and X-ray structures of Silyl(hydrido)zirconocene derivatives". . p. 8564 - 8566. Retrieved 2007/10/02.