Silane, tris(1-methylethyl)(2-phenylethenyl)-, (E)-

Base Information

• Chemical Name: Silane, tris(1-methylethyl)(2-phenylethenyl)-, (E)-
• CAS No.: 76372-98-0
• Molecular Formula: C17H28Si
• Molecular Weight: 260.495
• Mol file: 76372-98-0.mol

Synonyms:

Chemical Property of Silane, tris(1-methylethyl)(2-phenylethenyl)-, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, tris(1-methylethyl)(2-phenylethenyl)-, (E)-

There total 10 articles about Silane, tris(1-methylethyl)(2-phenylethenyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

chlorotriisopropylsilane (6485-79-6) + 4-methylphenylstyryl sulfide (92550-70-4) → trans-2-triisopropylsilyl-1-phenylethylene (76372-98-0)

Guidance literature:

With tert-Butyl peroxybenzoate; In tert-butyl alcohol; at 110 ℃;

DOI:10.1021/acs.orglett.7b00126

Reference yield: 77.0%

chlorotriisopropylsilane (6485-79-6) + (E)-3-phenylacrylic acid (140-10-3) → trans-2-triisopropylsilyl-1-phenylethylene (76372-98-0)

Guidance literature:

With tert.-butylhydroperoxide; nickel(II) dimethylglyoximate; In decane; at 60 ℃; for 12h; regioselective reaction;

DOI:10.1002/aoc.5192

Reference yield: 75.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + chlorotriisopropylsilane (6485-79-6) → trans-2-triisopropylsilyl-1-phenylethylene (76372-98-0)

Guidance literature:

With di-tert-butyl peroxide; copper diacetate; In tert-butyl alcohol; at 110 ℃; for 24h; stereoselective reaction; Inert atmosphere;

DOI:10.1039/c6cc05509e

upstream raw materials:

styrene

chlorotriisopropylsilane

phenylacetylene

4-methylphenylstyryl sulfide

Refernces

• 1、 Jiang, Wei,Zhang, Yongxin,Su, Yingpeng,Bao, Xiazhen,Fu, Ying,Huo, Congde. "Oxidative Dehydrogenative Silylation-Alkenation Reaction of Alkyl Aromatics with Silanes". supporting information. p. 1065 - 1069. Retrieved 2020/06/25.
• 2、 Gee, Jack C.,Fuller, Beth A.,Lockett, Hannah-Marie,Sedghi, Gita,Robertson, Craig M.,Luzyanin, Konstantin V.. "Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts". supporting information. p. 9450 - 9453. Retrieved 2018/08/28.