92550-70-4

Basic information

• Product Name: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-
• CAS NO: 92550-70-4
• Molecular Formula: C15H14S
• Molecular Weight: 226.342
• Mol File: 92550-70-4.mol
• Article Data: 43

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-(92550-70-4)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-(92550-70-4)

Safety Data

• Hazardous Substances Data: 92550-70-4(Hazardous Substances Data)

Upstream product

• 10486-08-5 sodium p-thiocresolate 
• 536-74-3 phenylacetylene 
• 141-52-6 sodium ethanolate 
• 106-45-6 para-thiocresol 
• 2757-04-2 phenyl cinnamate 
• 933-00-6 p-methylbenzenesulfenyl chloride 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 103-19-5 di(p-tolyl) disulfide 
• 588-73-8 (Z)-β-bromostyrene 
• 7361-89-9 di-n-propyl diselenide 
• 103-64-0 bromostyrene 
• 1945-84-2 2-ethynylpyridine 
• 873-73-4 4-n-chlorophenylacetylene 
• 766-49-4 (2-fluorophenyl)acetylene 

Downstream Products

• 42883-88-5 Phenyl(p-Tolylthio)acetaldehyd 
• 41103-85-9 (E)-1-methyl-4-(styrylsulfinyl)benzene 
• 479623-83-1 (+/-)-(Z)-5-phenyl-4-(p-tolylsulfenyl)pent-4-en-3-ol 
• 19062-76-1 (1-phenyl-2-tosylethyl)-(p-tolyl)sulfane 
• 2779-69-3 1,1-dichloro-2,2-diphenylethene 
• 19719-87-0 1-methyl-4-(phenethylsulfonyl)benzene 
• 211929-53-2 (2-tosylethane-1,1-diyl)dibenzene 
• 1068599-48-3 CH₃C₆H₄SCHCH₂C₆H₅BO₂C₆H₄ 
• 156575-60-9 2-(1-phenyl-ethyl)-benzo[1,3,2]dioxaborole 
• 1068599-50-7 CH₃C₆H₄SCH₂CHBO₂C₆H₄C₆H₅ 
• 3582-84-1 (2-phenylethyl)diphenylphosphine oxide 
• 15436-11-0 (E)-methyl styryl sulfone 
• 795-47-1 (E)-diphenyl(styryl)phosphine oxide 

Relevant articles and documents

Redox-active benzimidazolium sulfonamides as cationic thiolating reagents for reductive cross-coupling of organic halides

Redox-active benzimidazolium sulfonamides as thiolating reagents have been developed for reductive C-S bond coupling. The IMDN-SO2R reagent provides a bench-stable cationic precursor to generate a portfolio of highly active N-S intermediates, which can be successfully applied in cross-electrophilic coupling with various organic halides. The employment of an electrophilic sulfur source solved the problem of catalyst deactivation and avoided odorous thiols, featuring practical conditions, broad substrate scope, and excellent tolerance.

Transition Metal-Free C-H Thiolation via Sulfonium Salts Using β-Sulfinylesters as the Sulfur Source

We disclose a direct C(sp)-, C(sp2)-, and C(sp3)-H thiolation reaction using β-sulfinylesters as the versatile sulfur source. The key step of this protocol is chemoselective C-S bond cleavage of the sulfonium salts that are formed in situ from the corresponding alkenes, alkynes, and 1,3-dicarboxyl compounds with β-sulfinylesters. The successful capture of the acrylate byproduct supports a retro-Michael reaction mechanism.

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.