1,1':3',1''-Terphenyl, 3-nitro-

Base Information

• Chemical Name: 1,1':3',1''-Terphenyl, 3-nitro-
• CAS No.: 78626-53-6
• Molecular Formula: C18H13NO2
• Molecular Weight: 275.307
• Mol file: 78626-53-6.mol

Synonyms:

Chemical Property of 1,1':3',1''-Terphenyl, 3-nitro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1':3',1''-Terphenyl, 3-nitro-

There total 1 articles about 1,1':3',1''-Terphenyl, 3-nitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

m-iodonitrobenzene (645-00-1) + 3-iodo-1,1'-biphenyl (20442-79-9) → 3,3'-dinitro-1,1'-biphenyl (958-96-3) + meta-quaterphenyl (1166-18-3) + 1‐(3‐nitrophenyl)‐3‐phenylbenzene (78626-53-6)

Guidance literature:

With copper; at 225 ℃; for 1h;

Reference yield:

1‐(3‐nitrophenyl)‐3‐phenylbenzene (78626-53-6) → 2'''-amino-m-septiphenyl (78626-86-5)

Guidance literature:

Multi-step reaction with 4 steps

1: 97 percent / 1.) activated iron; 2.) hydrogen chloride / benzene

2: 1.) sodium nitrite, conc. H₂SO₄; 2.) potassium iodide / 1.) water, 0-5 deg C, 1.5 h; 2.) water to 80 deg C

3: 1.16 g / copper powder / 1 h / 240 - 245 °C

4: 95 percent / activated iron / benzene

With hydrogenchloride; sulfuric acid; iron; copper; potassium iodide; sodium nitrite; In benzene;

Reference yield:

1‐(3‐nitrophenyl)‐3‐phenylbenzene (78626-53-6) → 2'''-nitro-m-septiphenyl (78626-85-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 97 percent / 1.) activated iron; 2.) hydrogen chloride / benzene

2: 1.) sodium nitrite, conc. H₂SO₄; 2.) potassium iodide / 1.) water, 0-5 deg C, 1.5 h; 2.) water to 80 deg C

3: 1.16 g / copper powder / 1 h / 240 - 245 °C

With hydrogenchloride; sulfuric acid; iron; copper; potassium iodide; sodium nitrite; In benzene;

upstream raw materials:

m-iodonitrobenzene

3-iodo-1,1'-biphenyl

Downstream raw materials:

m-sexiphenyl

m-septiphenyl

2'''-amino-m-septiphenyl

2'''-nitro-m-septiphenyl

Refernces