2,6,9,10-Anthracenetetracarbonitrile

Base Information

• Chemical Name: 2,6,9,10-Anthracenetetracarbonitrile
• CAS No.: 80721-78-4
• Molecular Formula: C18H6N4
• Molecular Weight: 278.272
• DSSTox Substance ID: DTXSID70451424
• Nikkaji Number: J606.476K
• Wikidata: Q82271443
• Mol file: 80721-78-4.mol

Synonyms:2,6,9,10-Anthracenetetracarbonitrile;80721-78-4;2,6,9,10-tetracyanoanthracene;Anthracene-2,6,9,10-tetracarbonitrile;SCHEMBL149913;3,7,9,10-Tetracyanoanthracene;DTXSID70451424

Chemical Property of 2,6,9,10-Anthracenetetracarbonitrile

Chemical Property:

• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 278.059246208
• Heavy Atom Count: 22
• Complexity: 586

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC2=C(C=C1C#N)C(=C3C=CC(=CC3=C2C#N)C#N)C#N

Technology Process of 2,6,9,10-Anthracenetetracarbonitrile

There total 63 articles about 2,6,9,10-Anthracenetetracarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

meso-1,2-bis(4-dimethylaminophenyl)-1,2-ethanediol (86001-22-1) + 2,6,9,10-tetracyanoanthracene (80721-78-4) → 2,6,9,10-tetracyanoanthracene radical anion (80721-78-4) + 4-dimethylamino-benzaldehyde (100-10-7)

Guidance literature:

In acetonitrile; Quantum yield; Mechanism; Rate constant; Ambient temperature; Irradiation;

DOI:10.1021/j100011a025

Reference yield:

1,2-bis[4-(dimethylamino)phenyl]-1,2-ethanediol (54322-62-2,86001-21-0,86001-22-1) + 2,6,9,10-tetracyanoanthracene (80721-78-4) → 2,6,9,10-tetracyanoanthracene radical anion (80721-78-4) + 4-dimethylamino-benzaldehyde (100-10-7)

Guidance literature:

In acetonitrile; Quantum yield; Mechanism; Rate constant; Ambient temperature; Irradiation;

DOI:10.1021/j100011a025

Reference yield:

Anthracene-2,6,9,10-tetracarbonitrile; compound with 1,2,3,4,5,6-hexamethyl-benzene (130563-76-7) → Hexamethylbenzene (87-85-4) + 2,6,9,10-tetracyanoanthracene (80721-78-4)

Guidance literature:

In acetonitrile; Thermodynamic data; Rate constant; ΔG;

DOI:10.1021/ja00167a027

upstream raw materials:

Anthracene-2,6,9,10-tetracarbonitrile; compound with m-xylene

Anthracene-2,6,9,10-tetracarbonitrile; compound with p-xylene

Anthracene-2,6,9,10-tetracarbonitrile; compound with mesitylene

Anthracene-2,6,9,10-tetracarbonitrile; compound with 1,2,4-trimethyl-benzene

Downstream raw materials:

fluorene radical cation

Naphthalene

biphenyl

1,2-dimethylbenzene radica cation

Refernces

• 1、 Gould, Ian R.,Farid, Samir. "Steric Effects in Photoinduced Electron-Transfer Reactions". . p. 13067 - 13072. Retrieved 2007/10/02.
• 2、 Gould, Ian R.,Ege, Deniz,Moser, Jacques E.,Farid, Samir. "Efficiencies of photoinduced electron-transfer reactions: Role of the Marcus inverted region in return electron transfer within geminate radical-ion pairs". . p. 4290 - 4301. Retrieved 2007/10/02.