4-Benzoylphenyl acrylate

Base Information

• Chemical Name: 4-Benzoylphenyl acrylate
• CAS No.: 22535-49-5
• Molecular Formula: C16H12O3
• Molecular Weight: 252.269
• Hs Code.: 2916129000
• European Community (EC) Number: 805-629-1
• DSSTox Substance ID: DTXSID2066808
• Nikkaji Number: J39.685K
• Wikidata: Q72436462
• Mol file: 22535-49-5.mol

Synonyms:4-Benzoylphenyl acrylate;22535-49-5;4-Acryloyloxybenzophenone;2-Propenoic acid, 4-benzoylphenyl ester;(4-benzoylphenyl) prop-2-enoate;2-PROPENOIC ACID,4-BENZOYLPHENYL ESTER;4-Acryloxybenzophenone;4-Benzoylphenylacrylate;para-acryloxybenzophenone;4-acryloyloxy benzophenone;4-acryloyloxy-benzophenone;4-(Acryloyloxy)benzophenone;SCHEMBL39494;DTXSID2066808;LTYBJDPMCPTGEE-UHFFFAOYSA-N;AMY18737;XAA53549;MFCD12828285;AKOS016005078;DS-4097;CS-0158048;FT-0728327;4-acryloyloxybenzophenone;A878514

Chemical Property of 4-Benzoylphenyl acrylate

Chemical Property:

• Vapor Pressure: 7.77E-07mmHg at 25°C
• Melting Point: 48.5 °C(Solv: hexane (110-54-3))
• Refractive Index: 1.576
• Boiling Point: 407.043 °C at 760 mmHg
• Flash Point: 181.355 °C
• PSA: 43.37000
• Density: 1.164 g/cm³
• LogP: 3.00900
• Storage Temp.: 2-8°C
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 252.078644241
• Heavy Atom Count: 19
• Complexity: 334

Purity/Quality:

99%, ^*data from raw suppliers

4-Benzoylphenylacrylate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OC1=CC=C(C=C1)C(=O)C2=CC=CC=C2

Technology Process of 4-Benzoylphenyl acrylate

There total 4 articles about 4-Benzoylphenyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

acryloyl chloride (814-68-6,25189-84-8) + 4-Hydroxybenzophenone (1137-42-4) → acrylic acid 4-benzoylphenyl ester (22535-49-5)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.jphotochem.2011.01.012

Reference yield:

3-chloro-propionic acid 4-benzoylphenyl ester (1159136-25-0) → acrylic acid 4-benzoylphenyl ester (22535-49-5)

Guidance literature:

With 2,6-di-tert-butyl-4-methyl-phenol; potassium carbonate; In acetone; for 2h; Heating / reflux;

Reference yield:

2-chloropropionyl chloride (625-36-5) + 4-Hydroxybenzophenone (1137-42-4) → acrylic acid 4-benzoylphenyl ester (22535-49-5)

Guidance literature:

With triethylamine; In dichloromethane; water; Temperature; Flow reactor;

upstream raw materials:

3-chloro-propionic acid 4-benzoylphenyl ester

acryloyl chloride

4-Hydroxybenzophenone

Methacryloyl chloride

Refernces

• 1、 -. "METHODS OF MAKING BENZOPHENONYL(ALK)ACRYLIC ESTERS AND SUBSTITUTED BENZOPHENONYL(ALK)ACRYLIC ESTERS IN FLOW REACTORS". Page/Page column 30. . Retrieved 2019/01/08.
• 2、 -. "COPOLYMERIZABLE PHOTOINITIATORS". Page/Page column. . Retrieved 2015/07/02.