Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride

Base Information

• Chemical Name: Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride
• CAS No.: 27639-98-1
• Molecular Formula: C12F24O4
• Molecular Weight: 664.091
• Hs Code.: 2918999090
• European Community (EC) Number: 673-685-2
• DSSTox Substance ID: DTXSID40880242
• Nikkaji Number: J34.424I
• Mol file: 27639-98-1.mol

Synonyms:27639-98-1;Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride;Perfluoro(2,5,8-trimethyl-3,6,9-trioxadodecanoyl) fluoride;2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]propanoyl fluoride;3,6,9-Trioxadodecanoyl fluoride, tetradecafluoro-2,5,8-tris(trifluoromethyl)-;Perfluoro(2,5,8-trimethyl-3,6,9-trioxadodecanoyl)fluoride;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy)propoxy)-;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy)propoxy)-;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy]propoxy]-;Hfpo tatramer acid fluoride;SCHEMBL3475062;AMY6856;DTXSID40880242;C12F24O4;CBA63998;MFCD00084743;AKOS005064049;C12-F24-O4;AS-77297;Propanoyl fluoride,2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]-;CS-0121621;FT-0651940;A819142;Perfluoro(2,5,8-trimethyl-3,6,9-trioxadodecanoyl)-fluoride;2,5,8-Tris(trifluoromethyl)-3,6,9-trioxatetradecafluorododecanoic acid fluoride;2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)propoxy)propanoyl fluoride

Chemical Property of Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride

Chemical Property:

• Vapor Pressure: 0.00633mmHg at 25°C
• Refractive Index: 1.283
• Boiling Point: 271.8 °C at 760 mmHg
• Flash Point: 114.6 °C
• PSA: 44.76000
• Density: 1.775 g/cm³
• LogP: 7.19260
• Sensitive.: Moisture Sensitive
• XLogP3: 8.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 28
• Rotatable Bond Count: 10
• Exact Mass: 663.9413344
• Heavy Atom Count: 40
• Complexity: 928

Purity/Quality:

98%,99%, ^*data from raw suppliers

Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(OC(C(C(F)(F)F)(OC(C(C(F)(F)F)(OC(C(C(F)(F)F)(F)F)(F)F)F)(F)F)F)(F)F)F)F
• Uses: Perfluoro(2,5,8-trimethyl-3,6,9-trioxadodecanoyl) Fluoride is a useful for the preparation of fluorinated imide salt compounds for surfactants.

Technology Process of Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride

There total 3 articles about Perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

Hexafluoropropene oxide (428-59-1,25038-02-2) → 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,17,18,18,18-Eicosafluoro-3,6,9,12,15-pentaoxa-2,5,8,11,14-pentakis(trifluoromethyl)octadecanoyl fluoride (13252-15-8) + 2,4,4,5,7,7,8,10,10,11,11,12,12,12-Tetradecafluoro-3,6,9-trioxa-2,5,8-tris(trifluoromethyl)dodecanoyl fluoride (27639-98-1) + 2,4,4,5,7,7,8,10,10,11,13,13,14,14,15,15,15-Heptadecafluoro-3,6,9,12-tetraoxa-2,5,8,11-tetrakis(trifluoromethyl)pentadecanoyl fluoride (34761-47-2) + perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride (2641-34-1)

Guidance literature:

With potassium fluoride; In diethylene glycol dimethyl ether; for 24h; Further byproducts given; Ambient temperature;

DOI:10.1016/S0022-1139(00)80953-7

Reference yield: 10.0%

Hexafluoropropene oxide (428-59-1,25038-02-2) → perfluoro(2-propoxypropionyl) fluoride (2062-98-8,125037-08-3,75566-60-8) + 2,4,4,5,7,7,8,10,10,11,11,12,12,12-Tetradecafluoro-3,6,9-trioxa-2,5,8-tris(trifluoromethyl)dodecanoyl fluoride (27639-98-1) + 2,4,4,5,7,7,8,10,10,11,13,13,14,14,15,15,15-Heptadecafluoro-3,6,9,12-tetraoxa-2,5,8,11-tetrakis(trifluoromethyl)pentadecanoyl fluoride (34761-47-2) + perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride (2641-34-1)

Guidance literature:

With potassium fluoride; In diethylene glycol dimethyl ether; for 24h; Further byproducts given; Ambient temperature;

DOI:10.1016/S0022-1139(00)80953-7

Reference yield:

Hexafluoropropene oxide (428-59-1,25038-02-2) → 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,17,18,18,18-Eicosafluoro-3,6,9,12,15-pentaoxa-2,5,8,11,14-pentakis(trifluoromethyl)octadecanoyl fluoride (13252-15-8) + 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,19,19,20,20,21,21,21-Tricosafluoro-3,6,9,12,15,18-hexaoxa-2,5,8,11,14,17-hexakis(trifluoromethyl)heneicosanoyl fluoride (13140-24-4) + 2,4,4,5,7,7,8,10,10,11,11,12,12,12-Tetradecafluoro-3,6,9-trioxa-2,5,8-tris(trifluoromethyl)dodecanoyl fluoride (27639-98-1) + 2,4,4,5,7,7,8,10,10,11,13,13,14,14,15,15,15-Heptadecafluoro-3,6,9,12-tetraoxa-2,5,8,11-tetrakis(trifluoromethyl)pentadecanoyl fluoride (34761-47-2)

Guidance literature:

With potassium fluoride; ethyl fluorooxolate; In diethylene glycol dimethyl ether; for 14h; Yield given. Further byproducts given. Yields of byproduct given; Heating;

DOI:10.1016/S0022-1139(96)03511-7

upstream raw materials:

Hexafluoropropene oxide

Downstream raw materials:

perfluoro-(2,5,8-trimethyl-3,6,9-trioxadodecanoic)acid

2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-heptafluoropropyloxy-propoxy)-propoxy]-propionic acid ethyl ester

C₁₉H₆Br₂F₂₃NO₄

Perfluoro-5,8,11,12,15,18-hexamethyl-4,7,10,13,16,19-hexaoxadocosane

Refernces

• 1、 Ishikawa, Nobuo,Sasabe, Mikio. "SURFACE ACTIVE SUBSTANCES CONTAINING AN OLIGO(HEXAFLUOROPROPENE OXIDE) CHAIN AS A HYDROPHOBIC AND OLEOPHOBIC MOIETY". . p. 241 - 254. Retrieved 2007/10/02.