Hexafluoropropene oxide trimer

Base Information

• Chemical Name: Hexafluoropropene oxide trimer
• CAS No.: 2641-34-1
• Deprecated CAS: 514807-04-6
• Molecular Formula: C9F18O3
• Molecular Weight: 498.068
• European Community (EC) Number: 220-141-3
• UNII: 6MU15P9EJN
• DSSTox Substance ID: DTXSID2044630
• Nikkaji Number: J26.715E
• Wikidata: Q27265174
• Mol file: 2641-34-1.mol

Synonyms:2641-34-1;Hexafluoropropene oxide trimer;2,5-Bis(trifluoromethyl)-3,6-dioxaundecafluorononanoyl Fluoride;EINECS 220-141-3;UNII-6MU15P9EJN;6MU15P9EJN;Perfluoro(2,5-dimethyl-3,6-dioxanonanoyl) fluoride;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy)-;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy]-;Propionyl fluoride, tetrafluoro-2-(hexafluoro-2-(heptafluoropropoxy)propoxy)-;2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)propanoyl fluoride;2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propanoyl fluoride;Propionyl fluoride, tetrafluoro-2-[hexafluoro-2-(heptafluoropropoxy)propoxy]-;2,3,3,3-Tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy)propionyl fluoride;2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy]propionyl fluoride;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy)-;Propanoyl fluoride, 2-(1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy)-2,3,3,3-tetrafluoro-;PROPIONYL FLUORIDE, 2,3,3,3-TETRAFLUORO-2-(1,1,2,3,3,3-HEXAFLUORO-2-(HEPTAFLUOROPROPOXY)PROPOXY)-;Propionyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy]-;SCHEMBL428731;DTXSID2044630;C9F18O3;MFCD00054658;AKOS005063689;CS-W011455;AS-75639;CF3CF2CF2OCF(CF3)CF2OCF(CF3)COF;FCOCF(CF3)OCF2CF(CF3)OCF2CF2CF3;CF3(CF2)2OCF(CF3)CF2OCF(CF3)COF;LS-123214;B1698;FT-0634421;Perfluoro-(2,5-dimethyl-3,6-dioxanonanal);H11409;Perfluoro(2,5-dimethyl-3,6-dioxanonan-1-one);Perfluoro(2,5-dimethyl-3,6-dioxananoyl)fluoride;A818429;Perfluoro(2,5-dimethyl-3,6-dioxananoyl) fluoride;Perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride;Q27265174;perfluoro-2-(2-methyl-3-oxahexyloxy)-propionyl fluoride;2,5-Bis(trifluoromethyl)undecafluoro-3,6-dioxanonanoic acid fluoride;2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]-propanoyl fluoride;2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propanoyl fluoride #;PROPANOYL FLUORIDE,2,3,3,3-TETRAFLUORO-2-[1,1,2,3,3,3-HEXAFLUORO-2-(1,1,2,2,3,3,3-HEPTAFLUOROPROPOXY)PROPOXY]-

Chemical Property of Hexafluoropropene oxide trimer

Chemical Property:

• Vapor Pressure: 0.392mmHg at 25°C
• Refractive Index: 1.279
• Boiling Point: 196.8 °C at 760 mmHg
• Flash Point: 71.1 °C
• PSA: 35.53000
• Density: 1.745 g/cm³
• LogP: 5.35510
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Moisture Sensitive
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• XLogP3: 6.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 7
• Exact Mass: 497.9560008
• Heavy Atom Count: 30
• Complexity: 645

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,5-Bis(trifluoromethyl)-3,6-dioxaundecafluorononanoyl Fluoride >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(OC(C(C(F)(F)F)(OC(C(C(F)(F)F)(F)F)(F)F)F)(F)F)F)F

Technology Process of Hexafluoropropene oxide trimer

There total 15 articles about Hexafluoropropene oxide trimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

C12F24O4 + C12HF23O4 (395058-38-5) → perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride (2641-34-1) + Hexafluoroacetone (684-16-2)

Guidance literature:

With potassium fluoride; at 200 ℃; for 2h; Autoclave;

DOI:10.1246/bcsj.80.1611

Reference yield: 36.0%

→ perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride (2641-34-1)

Guidance literature:

Reference yield: 27.0%

Hexafluoropropene oxide (428-59-1,25038-02-2) → 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,17,18,18,18-Eicosafluoro-3,6,9,12,15-pentaoxa-2,5,8,11,14-pentakis(trifluoromethyl)octadecanoyl fluoride (13252-15-8) + 2,4,4,5,7,7,8,10,10,11,11,12,12,12-Tetradecafluoro-3,6,9-trioxa-2,5,8-tris(trifluoromethyl)dodecanoyl fluoride (27639-98-1) + 2,4,4,5,7,7,8,10,10,11,13,13,14,14,15,15,15-Heptadecafluoro-3,6,9,12-tetraoxa-2,5,8,11-tetrakis(trifluoromethyl)pentadecanoyl fluoride (34761-47-2) + perfluoro-2,5-dimethyl-3,6-dioxanonanoyl fluoride (2641-34-1)

Guidance literature:

With potassium fluoride; In diethylene glycol dimethyl ether; for 24h; Further byproducts given; Ambient temperature;

DOI:10.1016/S0022-1139(00)80953-7

upstream raw materials:

Hexafluoropropene oxide

Caesium; 1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-heptafluoropropyloxy-propoxy)-propan-1-olate

C₂₀F₃₄O₄

C₁₂HF₂₃O₄

Downstream raw materials:

1,1,1,2,3,3-hexafluoro-2-(heptafluoropropoxy)-3-[(trifluorovinyl)oxy]propane

perfluoropropionic acid methyl ester

methyl undecafluoro-2-methyl-3-oxahexanoate

perfluoropropanoyl fluoride

Refernces

• 1、 -. "Hydrofluoroether compound and its preparation method and application (by machine translation)". Paragraph 0074-0076. . Retrieved 2019/04/26.
• 2、 -. "FLUORINATED ADAMANTANE DERIVATIVES". Page/Page column 23. . Retrieved 2008/06/13.