Benzene, 4-hexenyl-, (E)-

Base Information

• Chemical Name: Benzene, 4-hexenyl-, (E)-
• CAS No.: 828-14-8
• Molecular Formula: C12H16
• Molecular Weight: 160.259
• Mol file: 828-14-8.mol

Synonyms:

Chemical Property of Benzene, 4-hexenyl-, (E)-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 4-hexenyl-, (E)-

There total 26 articles about Benzene, 4-hexenyl-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1-chloro-1-methyl-5-phenylpentyl p-tolyl sulfoxide (420110-25-4) → (E)-hex-4-en-1-ylbenzene (828-14-8)

Guidance literature:

With tert.-butyl lithium; In tetrahydrofuran; at -75 ℃; for 0.0833333h;

DOI:10.1016/0040-4020(95)01078-5

Reference yield: 79.0%

C17H25BO2 (154820-97-0) + methyl iodide (74-88-4) → (E)-hex-4-en-1-ylbenzene (828-14-8)

Guidance literature:

With C₂₁H₃₀ClNPPd; potassium tert-butylate; In tert-Amyl alcohol; at 65 ℃; for 18h; Sealed tube; Inert atmosphere; Glovebox;

DOI:10.1021/acs.orglett.9b00025

Reference yield: 67.0%

2-(dimethylphenylsilyl)-6-phenylhex-2-ene (817628-43-6) + iodobenzene (591-50-4) → 2,6-diphenyl-Z-hex-2-ene + (E)-hex-4-en-1-ylbenzene (828-14-8)

Guidance literature:

2-(dimethylphenylsilyl)-6-phenylhex-2-ene; With 18-crown-6 ether; potassium trimethylsilonate; In tetrahydrofuran; at 20 ℃; for 0.00833333h;

iodobenzene; With tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; for 2h; Heating;

DOI:10.1021/jo048746t

upstream raw materials:

(E)-1-Bromo-2-butene

1-phenyl-2-bromoethane

1,4-Pentadiene

toluene

Refernces

• 1、 Meng, Qing-Yuan,Schirmer, Tobias E.,Katou, Kousuke,K?nig, Burkhard. "Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis". . p. 5723 - 5728. Retrieved 2019/04/03.
• 2、 Yamasaki, Naoto,Kanno, Marina,Sakamoto, Kyohei,Kasai, Yusuke,Imagawa, Hiroshi,Yamamoto, Hirofumi. "M -C2B10H11HgCl/AgOTf-Catalyzed Reaction for Reductive Deoxygenation". . p. 169 - 175. Retrieved 2018/03/26.