Benzoic acid, 4-nitro-, ethenyl ester

Base Information

• Chemical Name: Benzoic acid, 4-nitro-, ethenyl ester
• CAS No.: 831-69-6
• Molecular Formula: C9H7NO4
• Molecular Weight: 193.159
• Mol file: 831-69-6.mol

Synonyms:

Chemical Property of Benzoic acid, 4-nitro-, ethenyl ester

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 4-nitro-, ethenyl ester

There total 6 articles about Benzoic acid, 4-nitro-, ethenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

vinyl acetate (108-05-4,9003-20-7) + 4-nitro-benzoic acid (62-23-7) → ethenyl 4-nitrobenzoate (831-69-6)

Guidance literature:

With palladium diacetate; potassium hydroxide; at 20 ℃; Inert atmosphere;

DOI:10.1039/c1ob05739a

Reference yield: 70.0%

2,4,6-trivinylcyclotriboroxane*pyridine complex + 4-nitro-benzoic acid (62-23-7) → ethenyl 4-nitrobenzoate (831-69-6)

Guidance literature:

With N,N'-diethylurea; copper(II) bis(trifluoromethanesulfonate); triethylamine; In tetrahydrofuran; at 50 ℃; for 16h;

DOI:10.1002/adsc.201800914

Reference yield: 51.0%

vinyl acetate (108-05-4,9003-20-7) + (carbonic acid ethyl ester)-(4-nitro-benzoic acid )-anhydride (110175-83-2) → ethenyl 4-nitrobenzoate (831-69-6)

Guidance literature:

vinyl acetate; With potassium tert-butylate; In tetrahydrofuran; at -40 - -30 ℃; Inert atmosphere;

(carbonic acid ethyl ester)-(4-nitro-benzoic acid )-anhydride; In tetrahydrofuran; at -40 - -30 ℃; Inert atmosphere;

DOI:10.1002/hlca.201300396

upstream raw materials:

vinyl acetate

4-nitro-benzoic acid

4-nitro-benzoyl chloride

p-nitrobenzoic anhydride

Downstream raw materials:

5-O-p-nitrobenzoyl-1,2-dideoxy-D-ribose

Refernces

• 1、 Steemers, Luuk,Wijsman, Linda,van Maarseveen, Jan H.. "Regio- and Stereoselective Chan-Lam-Evans Enol Esterification of Carboxylic Acids with Alkenylboroxines". supporting information. p. 4241 - 4245. Retrieved 2018/10/02.
• 2、 Martinez-Montero, Saul,Fernandez, Susana,Sanghvi, Yogesh S.,Gotor, Vicente,Ferrero, Miguel. "An expedient biocatalytic procedure for abasic site precursors useful in oligonucleotide synthesis". experimental part. p. 5960 - 5966. Retrieved 2011/10/05.