9-Phenylphenanthrene

Base Information

• Chemical Name: 9-Phenylphenanthrene
• CAS No.: 844-20-2
• Molecular Formula: C20H14
• Molecular Weight: 254.331
• Hs Code.: 2902909090
• DSSTox Substance ID: DTXSID401004675
• Nikkaji Number: J736.337K
• Wikidata: Q82999780
• Mol file: 844-20-2.mol

Synonyms:9-Phenylphenanthrene;844-20-2;9-Phenyl phenanthrene;9-PhenyIphenanthrene;9-phenyl-phenanthrene;JGGISUSKZFMBOJ-UHFFFAOYSA-N;DTXSID401004675;AKOS015905740;FT-0656947;AB-131/42301449

Chemical Property of 9-Phenylphenanthrene

Chemical Property:

• Vapor Pressure: 8.98E-07mmHg at 25°C
• Boiling Point: 416.8°C at 760 mmHg
• Flash Point: 199.1°C
• PSA: 0.00000
• Density: 1.14g/cm³
• LogP: 5.66000
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 254.109550447
• Heavy Atom Count: 20
• Complexity: 314

Purity/Quality:

98%min ^*data from raw suppliers

9-PHENYLPHENANTHRENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC3=CC=CC=C3C4=CC=CC=C42

Technology Process of 9-Phenylphenanthrene

There total 134 articles about 9-Phenylphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-(phenylethynyl)-1,1'-biphenyl (10271-65-5) → 9-phenylphenanthrene (844-20-2)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); eosin y; In dichloromethane; at 20 ℃; for 72h; Sealed tube; Irradiation; Inert atmosphere;

DOI:10.1039/c6cc03725a

Reference yield: 80.0%

2-(phenanthrene-9-yl)aniline → benzo[e]acephenanthrylene (205-99-2) + 9-phenylphenanthrene (844-20-2)

Guidance literature:

With tert.-butylnitrite; In acetonitrile; at 20 ℃; for 10h; Concentration; Solvent; Reagent/catalyst;

DOI:10.1039/c6ob01235c

Reference yield: 78.0%

9-iodo-10-phenylphenanthrene (312612-61-6) → benzo[e]acephenanthrylene (205-99-2) + 9-phenylphenanthrene (844-20-2)

Guidance literature:

With palladium diacetate; cesium pivalate; bis-diphenylphosphinomethane; In N,N-dimethyl-formamide; at 110 ℃; for 48h;

DOI:10.1021/jo048788h

upstream raw materials:

piperidine

diethyl ether

9-chlorophenanthrene

phenyllithium

Downstream raw materials:

9,10-dihydro-9-phenylphenanthrane

2'-benzoyl[1,1'-biphenyl]-2-carboxylic acid

9-bromo-10-phenylphenanthrene

Refernces

• 1、 Alder et al.. "-". . . Retrieved 1954.
• 2、 Akhmetov, Vladimir,Amsharov, Konstantin,Feofanov, Mikhail,Sharapa, Dmitry I.. "Alumina-Mediated π-Activation of Alkynes". supporting information. p. 15420 - 15426. Retrieved 2021/09/30.
• 3、 Choudhury, Joyanta,Dutta, Tapas Kumar,Mandal, Tanmoy,Mohanty, Sunit. "Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C-H functionalization". supporting information. p. 10182 - 10185. Retrieved 2021/10/12.