TRIMETHYLSILYL PROPIONATE

Base Information

• Chemical Name: TRIMETHYLSILYL PROPIONATE
• CAS No.: 16844-98-7
• Molecular Formula: C6H14O2Si
• Molecular Weight: 146.261
• Hs Code.: 2931900090
• Mol file: 16844-98-7.mol

Synonyms:Silanol,trimethyl-, propanoate (9CI);Silanol, trimethyl-, propionate (7CI,8CI);Trimethylpropionoxysilane;Trimethylsilyl propanoate;Trimethylsilyl propionate;

Chemical Property of TRIMETHYLSILYL PROPIONATE

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 20mmHg at 25°C
• Refractive Index: 1.398
• Boiling Point: 114.4 °C at 760 mmHg
• Flash Point: 19.3 °C
• PSA: 26.30000
• Density: 0.876
• LogP: 1.77450
• Storage Temp.: 0-6°C

Purity/Quality:

98%Min ^*data from raw suppliers

Trimethylsilyl Propionate >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIMETHYLSILYL PROPIONATE

There total 16 articles about TRIMETHYLSILYL PROPIONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

ethyl trimethylsilyl ether (1825-62-3) + propionic acid anhydride (123-62-6) → trimethylsilyl propionate (16844-98-7)

Guidance literature:

With CBV₇₈₀; at 60 ℃; for 0.0833333h; Microwave irradiation;

Reference yield: 99.0%

Trimethylsilanol (1066-40-6) + propionic acid anhydride (123-62-6) → trimethylsilyl propionate (16844-98-7)

Guidance literature:

With iron perchlorate hexahydrate; at 25 ℃; for 0.5h; Time;

Reference yield: 96.0%

trimethylsilyl cyanide (7677-24-9) + propionic acid (802294-64-0,79-09-4) → trimethylsilyl propionate (16844-98-7)

Guidance literature:

at 25 ℃; for 0.0833333h;

DOI:10.1021/jo00368a030

upstream raw materials:

chloro-trimethyl-silane

sodium proprionate

silver⁽¹⁺⁾ propionate

propionic acid

Downstream raw materials:

1,1-bis(trimethylsilyloxy)prop-1-ene

chloro-trimethyl-silane

Ethyl propionate

(-)-(2S,3S)-3-hydroxy-2-methyl-3-phenylpropanoic acid

Refernces

• 1、 -. "Method for Producing Acyloxysilanes, Acyloxysilanes Obtained Thereby, and Use of Same". Paragraph 0131. . Retrieved 2018/03/25.
• 2、 Rotzoll, Sven,Ullah, Ehsan,G?rls, Helmar,Fischer, Christine,Langer, Peter. "One-pot synthesis of 3-hydroxymaleic anhydrides by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride". . p. 2647 - 2656. Retrieved 2007/10/03.