Chimassorb 119

Base Information

• Chemical Name: Chimassorb 119
• CAS No.: 106990-43-6
• Deprecated CAS: 155076-64-5,122177-25-7,370868-42-1,912617-67-5,122177-25-7,370868-42-1
• Molecular Formula: C₁₃₂H₂₅₀N₃₂
• Molecular Weight: 2285.65
• European Community (EC) Number: 401-990-0,600-792-3
• UNII: UBL01213LI
• DSSTox Substance ID: DTXSID9047122
• Nikkaji Number: J682.480C
• Wikidata: Q27290999
• Mol file: 106990-43-6.mol

Synonyms:Chimassorb 119;106990-43-6;Antioxidant 119;Chimassorb NOR 119;Lowilite 19;Sabostab 119FL;Tinuvin 119;Sabostab UV 119;UNII-UBL01213LI;HALS 11;UBL01213LI;1,5,8,12-Tetrakis[4,6-bis(N-butyl-N-1,2,2,6,6-pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl]-1,5,8,12-tetraazadodecane;N2,N2'-(Ethane-1,2-diyl)bis(N2-(3-((4,6-bis(butyl(1,2,2,6,6-pentamethylpiperidin-4-yl)amino)-1,3,5-triazin-2-yl)amino)propyl)-N4,N6-dibutyl-N4,N6-bis(1,2,2,6,6-pentamethylpiperidin-4-yl)-1,3,5-triazine-2,4,6-triamine);EC 401-990-0;1,5,8,12-Tetrakis(4,6-bis(N-butyl-N-1,2,2,6,6-pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl)-1,5,8,12-tetraazadodecane;1,5,8,12-Tetrakis[4,6-bis(N-butyl-N-1,2,2,6,6-pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl]-1,5,;N,N',N'',N'''-Tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine;1,3,5-Triazine-2,4,6-triamine, N,N'''-1,2-ethanediylbis(N-(3-((4,6-bis(butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino)-1,3,5-triazin-2-yl)amino)propyl)-N',N''-dibutyl-N',N''-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-;1,3,5-Triazine-2,4,6-triamine, N,N'''-1,2-ethanediylbis[N-[3-[[4,6-bis[butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino]-1,3,5-triazin-2-yl]amino]propyl]-N',N''-dibutyl-N',N''-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-;C132H250N32;SCHEMBL39027;DTXSID9047122;AKOS015915753;SB73225;1,3,5-Triazine-2,4,6-triamine,N,N'''-1,2-ethanediylbis[N-[3-[[4,6-bis[butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino]-1,3,5-triazin-2-yl]amino]propyl]-N',N''-dibutyl-N',N''-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-;AS-83407;C132-H250-N32;LS-186258;Q27290999;1,3,5-TRIAZINE-2,4,6-TRIAMINE, N,N"'-1,2-ETHANEDIYLBIS[N-[3-[[4,6-BIS[BUTYL(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)AMINO]-1,3,5-TRIAZIN-2-YL]AMINO]PROPYL]-N',N''-DIBUTYL-N',N"-BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)-;1,3,5-Triazine-2,4,6-triamine, N,N'''-(1,2-ethanediylbis(((4,6-bis(butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino)-1,3,5-triazin-2-yl)imino)-3,1-propanediyl))bis(N',N''-dibutyl-N',N''-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-;1,3,5-TRIAZINE-2,4,6-TRIAMINE, N,N'''-1,2-ETHANEDIYLBIS(N- (3-((4,6-BIS(BUTYL(1,2,2,6,6-PENTAMETHYL-4- PIPERIDINYL)AMINO)-1,3,5-TRIAZIN-2-YL)AMINO)PROPYL)-N',N''-;1,3,5-Triazine-2,4,6-triamine, N,N'''-1,2-ethanediylbis[N-[3-[[4,6-bis[butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino]-1,3,5-triazin-2-yl]amino]propyl]-N',N''-dibutyl-N',N''-bis(1,2,2,6,6-pentamethyl;1,3,5-TRIAZINE-2,4,6-TRIAMINE, N2,N2'-1,2-ETHANEDIYLBIS(N2- (3-((4,6-BIS(BUTYL(1,2,2,6,6-PENTAMETHYL-4-;1,3,5-TRIAZINE-2,4,6-TRIAMINE, N2,N2'-1,2-ETHANEDIYLBIS(N2- (3-((4,6-BIS(BUTYL(1,2,2,6,6-PENTAMETHYL-4- PIPERIDINYL)AMINO)-1,3,5-TRIAZIN-2-YL)AMINO)PROPYL)-N4,N6- DIBUTYL-N4,N6-BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)-;1,3,5-Triazine-2,4,6-triamine, N2,N2'-1,2-ethanediylbis(N2-(3-((4,6-bis(butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino)-1,3,5-triazin-2-yl)amino)propyl)-N4,N6-dibutyl-N4,N6-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-;1,5,8,12-TETRAKIS(4,6-BIS(N-BUTYL-N-1,2,2,6,6-PENTAMETHYL-4-PIPERIDYLAMINO)-1,3,5-TRIAZINE-2-YL)-1,5,8,12-TETRAAZADODECANE;N,N'"-1,2-ETHANEDIYLBIS[N-[3-[[4,6-BIS[BUTYL(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)AMINO]-1,3,5-TRIAZIN-2-YL]AMINO]PROPYL]-N'N"-DIBUTYL-N',N"-BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)-1,3,5-TRIAZINE-2,4,6-DIAMINE];N,N'''-1,2-ETHANEDIYLBIS[N-[3-[[4,6-BIS[BUTYL(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)AMINO]-1,3,5-TRIAZIN-2-YL]AMINO]PROPYL]-N',N''-DIBUTYL-N',N''-BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)-1,3,5-TRIAZINE-2,4,6-DIAMINE

Chemical Property of Chimassorb 119

Chemical Property:

• Melting Point: 146-150 °C
• Flash Point: 275°C
• PSA: 237.06000
• Density: 1.019g/cm³
• LogP: 25.45640
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: chloroform, methylene chloride, and toluene: ≥20 % (w
• XLogP3: 29.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 32
• Rotatable Bond Count: 55
• Exact Mass: 2285.05798095
• Heavy Atom Count: 164
• Complexity: 3790

Purity/Quality:

99%min ^*data from raw suppliers

1,5,8,12-Tetrakis[4,6-bis(N-butyl-N-1,2,2,6,6-pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl]-1,5,8,12-tetraazadodecane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): XiN
• Hazard Codes: Xi,N
• Statements: 43-51/53
• Safety Statements: 26-36-61-37-24-22

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN(C1CC(N(C(C1)(C)C)C)(C)C)C2=NC(=NC(=N2)NCCCN(CCN(CCCNC3=NC(=NC(=N3)N(CCCC)C4CC(N(C(C4)(C)C)C)(C)C)N(CCCC)C5CC(N(C(C5)(C)C)C)(C)C)C6=NC(=NC(=N6)N(CCCC)C7CC(N(C(C7)(C)C)C)(C)C)N(CCCC)C8CC(N(C(C8)(C)C)C)(C)C)C9=NC(=NC(=N9)N(CCCC)C1CC(N(C(C1)(C)C)C)(C)C)N(CCCC)C1CC(N(C(C1)(C)C)C)(C)C)N(CCCC)C1CC(N(C(C1)(C)C)C)(C)C
• Uses: Chimassorb 119 is used as a light/thermal stabilizer in olefin polymers intended for use in c ontact with food. 1,5,8,12-Tetrakis[4,6-bis(N-butyl-N-1,2,2,6,6-pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl]-1,5,8,12-tetraazadodecane is used as a light/thermal stabilizer in olefin polymers intended for use in contact with food.

Technology Process of Chimassorb 119

There total 3 articles about Chimassorb 119 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-s-triazine-6-yl]-1, 5,8,12-tetraazadodecane (80387-98-0) → N,N'-4,7-tetrakis[4,6-bis{N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino}-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine (106990-43-6)

Guidance literature:

With hydrogen; In 5,5-dimethyl-1,3-cyclohexadiene; water; at 100 ℃; for 6h; under 22502.3 Torr; Solvent; Pressure; Temperature; Inert atmosphere;

Reference yield: 96.0%

2-chloro-4,6-bis-[N-(1,2,2,6,6-pentamethyl-4-piperidyl)-butylamino]-1,3,5-triazine (75720-76-2) + N,N'-bis(3-aminopropyl)-1,2-diamine (10563-26-5) → N,N'-4,7-tetrakis[4,6-bis{N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino}-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine (106990-43-6)

Guidance literature:

With sodium hydroxide; In cyclohexane; water; at 100 ℃; for 6h; Reagent/catalyst; Temperature; Time; Solvent; Inert atmosphere;

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + 1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-s-triazine-6-yl]-1, 5,8,12-tetraazadodecane (80387-98-0) → N,N'-4,7-tetrakis[4,6-bis{N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino}-1,3,5-triazin-2-yl]-4,7-diazadecane-1,10-diamine (106990-43-6)

Guidance literature:

In water; for 8h; Reflux;

upstream raw materials:

formaldehyd

1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-s-triazine-6-yl]-1, 5,8,12-tetraazadodecane

formic acid

2-chloro-4,6-bis-[N-(1,2,2,6,6-pentamethyl-4-piperidyl)-butylamino]-1,3,5-triazine

Refernces

• 1、 -. "Hindered amine light stabilizer intermediate and preparation method of hindered amine light stabilizer". Page/Page column 11-14. . Retrieved 2021/01/29.
• 2、 -. "Method for preparing hindered amine light stabilizer 119 and derivatives of hindered amine light stabilizer 119". Paragraph 0025; 0028-0029; 0032. . Retrieved 2019/11/21.