TRICHLOROMETHYLTRICHLOROSILANE

Base Information

• Chemical Name: TRICHLOROMETHYLTRICHLOROSILANE
• CAS No.: 17760-13-3
• Molecular Formula: CCl6Si
• Molecular Weight: 252.815
• European Community (EC) Number: 241-747-4
• UNII: G7U45GV5FL
• DSSTox Substance ID: DTXSID8066262
• Nikkaji Number: J287.147E
• Wikidata: Q81992850
• Mol file: 17760-13-3.mol

Synonyms:(Trichloromethyl)trichlorosilane;Trichloro(trichloromethyl)silane;

Chemical Property of TRICHLOROMETHYLTRICHLOROSILANE

Chemical Property:

• Vapor Pressure: 0.366mmHg at 25°C
• Melting Point: 112-115 °C(lit.)
• Refractive Index: 1.508
• Boiling Point: 205 °C at 760 mmHg
• Flash Point: 93.7 °C
• PSA: 0.00000
• Density: 1.695 g/cm³
• LogP: 3.97100
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 251.787093
• Heavy Atom Count: 8
• Complexity: 75.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRICHOLROMETHYLTRICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C([Si](Cl)(Cl)Cl)(Cl)(Cl)Cl

Technology Process of TRICHLOROMETHYLTRICHLOROSILANE

There total 14 articles about TRICHLOROMETHYLTRICHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

Methyltrichlorosilane (75-79-6) → trichloromethyltrichlorosilane (17760-13-3)

Guidance literature:

With chlorine; In tetrachloromethane; Irradiation;

Reference yield: 85.9%

Methyltrichlorosilane (75-79-6) → (chloromethyl)trichlorosilane (1558-25-4) + trichloro(dichloromethyl)silane (1558-24-3) + trichloromethyltrichlorosilane (17760-13-3)

Guidance literature:

With chlorine; at 250 ℃; for 20h; Further Variations:; Temperatures; time; Product distribution;

DOI:10.1023/A:1012753203518

Reference yield: 37.0%

tetrachloromethane (56-23-5) + tetrabutyl-ammonium chloride (1112-67-0) → trichloromethyltrichlorosilane (17760-13-3) + C2Cl9Si(1-)*C16H36N(1+)

Guidance literature:

With hexachlorodisilane; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique; Heating;

DOI:10.1021/jacs.8b05950

upstream raw materials:

Methyltrichlorosilane

trichloromethyl silane

dimethylsilicon dichloride

tetrachloromethane

Downstream raw materials:

1,2-bis-(trichlorosilyl)acetylene

1.1-Dichlor-2-trichlorsilyl-cyclopropan

tetrachlorosilane

hexa-Si-chloro-Si,Si'-(1,2-dichloro-ethene-1,2-diyl)-bis-silane

Refernces

• 1、 Timms. "". . p. 387,388. Retrieved 1968.
• 2、 -. "NOVEL ECO-FRIENDLY INSECTICIDES BASED ON SILICON COMPOUNDS AND PROCESS OF PREPARATION THEREOF". Page/Page column 13. . Retrieved 2018/08/26.
• 3、 Jung, Dong Euy,Kang, Seung-Hyun,Han, Joon Soo,Lim, Weon Cheol,Park, Young-ae W.,Yoo, Bok Ryul. "Si-C coupling reaction of polychloromethanes with HSiCl3 in the presence of Bu4PCl: Convenient synthetic method for bis(chlorosilyl)methanes". . p. 3901 - 3906. Retrieved 2008/03/12.