N,N'-TRIMETHYLENE-1,10-*PHENANTHROLINIUM DIBROMIDE

Base Information

• Chemical Name: N,N'-TRIMETHYLENE-1,10-*PHENANTHROLINIUM DIBROMIDE
• CAS No.: 15302-99-5
• Molecular Formula: C15H14 N2 . 2 Br
• Molecular Weight: 382.098
• Hs Code.: 2933990090
• Mol file: 15302-99-5.mol

Synonyms:5H-[1,4]Diazepino[1,2,3,4-lmn][1,10]phenanthrolinediium,6,7-dihydro-, dibromide (8CI,9CI);5H-6,7-Dihydro[1,4]diazepino[1,2,3,4-l,m,n]-1,10-phenanthrolinium dibromide

Chemical Property of N,N'-TRIMETHYLENE-1,10-*PHENANTHROLINIUM DIBROMIDE

Chemical Property:

• Boiling Point: 477.1°Cat760mmHg
• Flash Point: 223.7°C
• PSA: 7.76000
• Density: 1.24g/cm³
• LogP: -4.02030

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N'-TRIMETHYLENE-1,10-*PHENANTHROLINIUM DIBROMIDE

There total 3 articles about N,N'-TRIMETHYLENE-1,10-*PHENANTHROLINIUM DIBROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,10-Phenanthroline (66-71-7) + 1,3-dibromo-propane (109-64-8) → 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-l,m,n][1,10]phenanthroline-4,8-diium dibromide (15302-99-5)

Guidance literature:

In chlorobenzene; at 70 - 120 ℃;

DOI:10.1080/00304948.2012.697745

Reference yield:

1,10-phenanthroline hydrate (5144-89-8) + 1,3-dibromo-propane (109-64-8) → 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-l,m,n][1,10]phenanthroline-4,8-diium dibromide (15302-99-5)

Guidance literature:

In toluene; at 70 - 110 ℃; for 4.25h;

DOI:10.1016/j.tetlet.2020.151966

Reference yield:

→ 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-l,m,n][1,10]phenanthroline-4,8-diium dibromide (15302-99-5)

Guidance literature:

(yield)80percent;

DOI:10.1016/S0040-4020(01)96338-0

upstream raw materials:

1,10-Phenanthroline

1,3-dibromo-propane

1,10-phenanthroline hydrate

Downstream raw materials:

C₃₆H₃₈B₂N₂O₄

2,9-diphenyl-1,10-phenanthroline

2,9-dichloro-[1,10]phenanthroline

2,9-bis-(4-methoxy-phenyl)-1,10-phenanthroline

Refernces

• 1、 Guo,Zheng,Jiang. "Improved synthesis of 2,9-dichloro-1,10-phenanthroline". . p. 392 - 396. Retrieved 2012.
• 2、 Annibale, Vincent T.,Batcup, Rhys,Bai, Tao,Hughes, Sarah J.,Song, Datong. "RuCp* complexes of ambidentate 4,5-diazafluorene derivatives: From linkage isomers to coordination-driven self-assembly". . p. 6511 - 6521. Retrieved 2013.
• 3、 Wang, Xue-Yuan,Ao, Yu-Fei,Wang, Qi-Qiang,Wang, De-Xian. "Synthesis, Structure, Property, and Dinuclear Cu(II) Complexation of Tetraoxacalix[2]arene[2]phenanthrolines". . p. 13461 - 13469. Retrieved 2018.
• 4、 Xiao, Youli,Chu, Lisa,Sanakis, Yiannis,Liu, Pinghua. "Revisiting the IspH catalytic system in the deoxyxylulose phosphate pathway: Achieving high activity". . p. 9931 - 9933. Retrieved 2009.
• 5、 Summers. "". . p. 5433. Retrieved 1968.
• 6、 Bonnet, Sylvestre,Spa, Silvia,Zheng, Sipeng,van Geest, Erik P.,van Ruitenbeek, Jan M.. "Highly Ordered, Self-Assembled Monolayers of a Spin-Crossover Complex with In-Plane Interactions". . p. 2814 - 2821. Retrieved 2021/07/07.
• 7、 -. "BIS-PHENANTHROLINE IRON MACROCYCLE COMPLEX FOR OXYGEN REDUCTION REACTION". Page/Page column 6; 48. . Retrieved 2020/09/27.