Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate

Base Information Edit

Chemical Name:Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate
CAS No.:87597-84-0
Molecular Formula:C21H29NO6
Molecular Weight:391.464
Hs Code.:
DSSTox Substance ID:DTXSID70561259
Nikkaji Number:J387.634I
Wikidata:Q82444977
Mol file:87597-84-0.mol

Synonyms:Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate;87597-84-0;DTXSID70561259

Suppliers and Price of Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate Edit

Chemical Property:

XLogP3:2.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:11
Exact Mass:391.19948764
Heavy Atom Count:28
Complexity:564

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)OC(=O)CCC(C(=O)OC(C)(C)C)NC(=O)C1=CC=C(C=C1)C=O
Isomeric SMILES:CC(C)(C)OC(=O)CC[C@@H](C(=O)OC(C)(C)C)NC(=O)C1=CC=C(C=C1)C=O

Technology Process of Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate

There total 2 articles about Di-tert-butyl N-(4-formylbenzoyl)-L-glutamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 32677-01-3
L-glutamic acid di-tert-butyl ester hydrochloride

: 619-66-9
4-Carboxybenzaldehyde

: 87597-84-0
di-tert-butyl N-(4-formylbenzoyl)-L-glutamate

Guidance literature:: 4-Carboxybenzaldehyde; With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; triethylamine; In dichloromethane; for 0.25h;

L-glutamic acid di-tert-butyl ester hydrochloride; With triethylamine; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1021/jm021062y

Reference yield:

: 16874-06-9
di-tert-butyl L-glutamate

: C₁₃H₁₄O₄

: 87597-84-0
di-tert-butyl N-(4-formylbenzoyl)-L-glutamate

Guidance literature:: With 4-methyl-morpholine; In N,N-dimethyl-formamide; Yield given; 1.) -15 deg C, 45 min, 2.) 20 deg C, 18 h;
DOI:10.1021/jm00368a023

Reference yield: 93.0%

: 87597-84-0
di-tert-butyl N-(4-formylbenzoyl)-L-glutamate

: 581785-31-1
di-tert-butyl N-(4-carboxybenzoyl)-L-glutamate

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In tert-butyl alcohol; for 3h;
DOI:10.1021/jm021062y