Silane, chlorodimethylpropyl-

Base Information

• Chemical Name: Silane, chlorodimethylpropyl-
• CAS No.: 17477-29-1
• Molecular Formula: C5H13ClSi
• Molecular Weight: 136.697
• Hs Code.: 29319000
• European Community (EC) Number: 241-492-9
• UNII: V62B8Z72PJ
• DSSTox Substance ID: DTXSID9066205
• Nikkaji Number: J208.377I
• Wikidata: Q81992791
• Mol file: 17477-29-1.mol

Synonyms:17477-29-1;n-Propyldimethylchlorosilane;Silane, chlorodimethylpropyl-;Propyldimethylchlorosilane;Chlorodimethylpropylsilane;Chloro-dimethyl-propylsilane;V62B8Z72PJ;CHLORODIMETHYL-N-PROPYLSILANE;EINECS 241-492-9;chlorodimethyl(propyl)silane;Dimethylpropylchlorosilane;dimethylpropylsilyl chloride;Dimethyl-n-propylchlorosilane;UNII-V62B8Z72PJ;SCHEMBL523637;DTXSID9066205;PROPYL(DIMETHYL)CHLOROSILANE;Chlorodimethyl-n-propylsilane, 97%;MFCD00039301;AKOS006228438;FS-5504;D1590;FT-0623616;D89889;EN300-7577320;Dimethyl-n-propylchlorosilane (dimethyl-n-propylsilylating agent)

Chemical Property of Silane, chlorodimethylpropyl-

Chemical Property:

• Vapor Pressure: 23.2mmHg at 25°C
• Refractive Index: n20/D 1.413
• Boiling Point: 114.8 °C at 760 mmHg
• Flash Point: 12.5 °C
• PSA: 0.00000
• Density: 0.864 g/cm³
• LogP: 2.84030
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 136.0475046
• Heavy Atom Count: 7
• Complexity: 52

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorodimethylpropylsilane [Dimethylpropylsilylating Agent] >99.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F; C
• Hazard Codes: F,C
• Statements: 11-34
• Safety Statements: 16-26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[Si](C)(C)Cl

Technology Process of Silane, chlorodimethylpropyl-

There total 15 articles about Silane, chlorodimethylpropyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

dimethylmonochlorosilane (1066-35-9) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → dimethylpropylsilyl chloride (17477-29-1)

Guidance literature:

dihydrogen hexachloroplatinate; In diethyl ether; under 6 Torr;

DOI:10.1002/hlca.19840670813

Reference yield: 80.0%

dimethylsilicon dichloride (75-78-5,30107-43-8) → dimethylpropylsilyl chloride (17477-29-1)

Guidance literature:

propyl bromide; With magnesium; In tetrahydrofuran; Heating / reflux;

dimethylsilicon dichloride; In tetrahydrofuran; for 24h; Heating / reflux;

Reference yield: 37.2%

dimethylmonochlorosilane (1066-35-9) + 3-chloroprop-1-ene (107-05-1) → dimethylpropylsilyl chloride (17477-29-1) + (3-chloropropyl)dimethylchlorosilane (10605-40-0) + dimethylsilicon dichloride (75-78-5,30107-43-8)

Guidance literature:

at 50 - 55 ℃; for 12h;

DOI:10.1016/S0022-328X(00)83695-5

upstream raw materials:

1,3-dimethyl-1,1,3,3-tetraethyldisiloxane

n-propylmagnesium bromide

dimethylsilicon dichloride

1,1-dimethylsilacyclobutane

Downstream raw materials:

dimethylpropylsilane

C₁₁H₁₇ISi

dimethylsilane

1,2-Di-n-propyl-tetramethyldisilan

Refernces

• 1、 Damrauer,R. et al.. "". . p. 1068 - 1069. Retrieved 1972.
• 2、 Riener, Korbinian,Meister, Teresa K.,Gigler, Peter,Herrmann, Wolfgang A.,Kühn, Fritz E.. "Mechanistic insights into the iridium-catalyzed hydrosilylation of allyl compounds". . p. 203 - 209. Retrieved 2015/10/12.
• 3、 Belyakova,Chernyshev,Storozhenko,Knyazev,Turkel'taub,Parshina,Kisin. "Hydrosilylation of cyclohexene and allyl chloride with trichloro-, dichloro(methyl)-, and chlorodimethylsilanes in the presence of Pt(0) complexes". . p. 925 - 930. Retrieved 2008/02/03.